2002
DOI: 10.1039/b200188h
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Synthesis of the first superstructured chiral corrole

Abstract: The synthesis of the first chiral superstructured corrole has been achieved by reacting an original bis(diaminophenyl)corrole with two chiral binaphthyl bis(acid chloride) handles.

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Cited by 27 publications
(12 citation statements)
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“…1 Although these macrocycles have been studied for many decades, it is only recently that several research groups have focused their attention on these compounds, 2,3 taking advantage of the significant advances achieved with respect to new synthetic protocols leading to triarylcorroles in high yield. 4,7 …”
Section: Introductionmentioning
confidence: 99%
“…1 Although these macrocycles have been studied for many decades, it is only recently that several research groups have focused their attention on these compounds, 2,3 taking advantage of the significant advances achieved with respect to new synthetic protocols leading to triarylcorroles in high yield. 4,7 …”
Section: Introductionmentioning
confidence: 99%
“…1,2 This interest is due to the striking characteristics of this macrocycle compared with the parent porphyrins, which make corrole interesting for both theoretical and application reasons. 13 …”
mentioning
confidence: 99%
“…Finally, a number of research groups, most notably Gryko and co-workers, have described a multistep version of the one-pot corrole synthesis, involving the isolation of an aryl dipyrromethane intermediate, for preparing trans-A 2 B-type meso-triaryl corroles (for example, [96] see Scheme 16). [97][98][99][100][101][102] The serendipitous discovery of one-pot syntheses of corrole ligands has catapulted corrole chemistry to a prominent position within coordination chemistry. A major finding in terms of the coordination chemistry of corroles prior to the discovery of the one-pot syntheses was the discovery by Vogel and co-workers that trianionic corrole ligands stabilize highvalent transition-metal ions such as Cu III [103] and Fe IV , [104] at least in a formal sense (that is, regardless of the exact description of its electronic structure).…”
Section: Angewandte Chemiementioning
confidence: 99%