Abstract:2-Chlorophenyl methanethiol undergoes air oxidation catalyzed by different selenides andyields the corresponding disulfide 1 in two polymorphic forms, 1a and 1b. In the molecular structures of the two new polymorphs of o,o -dichloro dibenzyl disulfide, the dihedral angles between the dibenzyl groups are 82.0(1) • , (1a), and 73.7(4) • , (1b), respectively [(1a): P-1, a = 8.424(2) Å, b = 8.838(2) Å, c = 10.5823(19) Å, α = 90.122(18) • , β = 112.19(2) • , γ = 95.19(2) • , V = 725.9(3) Å 3 ; (1b): P2 1 /n, a = 10… Show more
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.