Synthesis, spectroscopic and structural aspects of triphenylantimony(V) complex with internally functionalized acetylferroceneoxime: Crystal and molecular structures of [C5H5FeC5H4C(CH3)NO]2SbPh3 and C5H5FeC5H4C(CH3)NOH

Yin, Handong; Li, Quan; Li, Linwei

doi:10.1016/j.inoche.2008.06.017

Cited by 24 publications

(1 citation statement)

References 15 publications

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“…However, these compounds are applied at complexometric process and the various complexes synthesis. Some factors that lead to value oximes characteristic, is these material application at other material synthesis [6][7][8][9][10][11][12][13][14][15][16] . These compounds are used to identify aldehydes and ketenes.…”

Section: Introductionmentioning

confidence: 99%

Study of 2-(piperidine-1-ylmethyl)cyclohexanamine Structure Synthesis Based on Oxime Protected Compounds in Mannich Mechanism

Taheri¹,

Soleymani²,

Hosn³

et al. 2012

Orientjchem.

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ABSTRACT2-(piperidine-1-ylmethyl)cyclohexanone (PMC), 2-(piperidine-1-ylmethyl)cyclohexanone oxime (PMCO) structures and also 2-(piperidine-1-ylmethyl) cyclohexan amine (PMCA) structure were extracted using experimental methods of Mannich reaction, based on oxime protected compounds. The given structures were purified at the end of syntheses process, by chromatography column. Related structures were identified by using 13 C-NMR, 1 H-NMR, FT-IR and mass spectroscopy. Attained results showed that using oxime structure as an intermediate causes to increase the yield and also to increase reaction ratio attain final product. However, all the attained spectra approved existence of intermediate and the final product. In following, thermodynamic parameters for the products including energetic levels, HOMO and LUMO parameters, chemical hardness, electrophilicity and chemical potential for this structures were calculated by using the density functional theory in method and B3LYP/6-311G(d,p) level of theory.

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Section: Introductionmentioning

confidence: 99%

Study of 2-(piperidine-1-ylmethyl)cyclohexanamine Structure Synthesis Based on Oxime Protected Compounds in Mannich Mechanism

Taheri¹,

Soleymani²,

Hosn³

et al. 2012

Orientjchem.

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Synthesis, Structure and Reactions of Organometallic Derivatives of Oximes

Абеле

Lukevics

2010

Patai's Chemistry of Functional Groups

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Organometallic derivatives of oximes were reviewed. These derivatives were selected and presented according to the place of the metal in the periodic table. Formation and reactions of disalts of oximes of type RC(CHMR′)=NOM (R, R′ = H, alkyl, aryl) and monosalts of oximes of type RC(CHMR′)=NOR″ (R″ = alkyl, aryl, M = alkali metal) were presented. Synthesis and reactions of silicon, germanium, tin, phosphorus containing oximes were included too. Beside this, oxime metal derivatives (for example, oxime palladacycles) as valuable catalysts in organic synthesis were described. In addition, oxime metal complexes exhibit wide spectrum of biological activity. Using of technetium‐99m hexamethylpropyleneamineoxime (Ceretec TM ) and related oxime complexes in diagnosis was described. Silicon and tin oxime complexes as excellent agrochemical agents were presented. Some cobalt, platinium and silicon containing oxime ethers exhibit high antitumor and cytotoxic activity and will be perspective targets for the further investigations. Introduction Synthesis, Structure and Reactions of Organometallic Derivatives of Oximes Conclusions

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“Cage‐like” Carboxyl Bridged Octaphenyltetraantimony Compounds (SbPh₂)₄(μ‐O)₄(μ‐OH)₂(μ‐O₂CR)₂: Synthesis and Structural Characterization

Yin

Hong

et al. 2012

Zeitschrift anorg allge chemie

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The metal‐directed self‐assembly of biphenylantimony trichloride and homocarboxylic acids LH [L = 2‐CHO‐C6H4COO– (1), 2, 3‐2F‐C6H4COO– (2), 4‐CF3–C6H4COO– (3)] provided three novel tetranuclear organoantimony(V) complexes, which were characterized by elemental analysis, FT‐IR, 1H, and 13C NMR spectroscopy as well as melting point, and X‐ray single crystal analysis. In the molecular structure, four hexacoordinate antimony atoms are linked into a [Sb2(μ‐O)2]2(μ‐O)2 “cage” architecture by oxo‐bridges which are terminally bridged by two carboxyl groups.

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Synthesis, spectroscopic and structural aspects of triphenylantimony(V) complex with internally functionalized acetylferroceneoxime: Crystal and molecular structures of [C5H5FeC5H4C(CH3)NO]2SbPh3 and C5H5FeC5H4C(CH3)NOH

Cited by 24 publications

References 15 publications

Study of 2-(piperidine-1-ylmethyl)cyclohexanamine Structure Synthesis Based on Oxime Protected Compounds in Mannich Mechanism

Study of 2-(piperidine-1-ylmethyl)cyclohexanamine Structure Synthesis Based on Oxime Protected Compounds in Mannich Mechanism

Synthesis, Structure and Reactions of Organometallic Derivatives of Oximes

“Cage‐like” Carboxyl Bridged Octaphenyltetraantimony Compounds (SbPh₂)₄(μ‐O)₄(μ‐OH)₂(μ‐O₂CR)₂: Synthesis and Structural Characterization

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Synthesis, spectroscopic and structural aspects of triphenylantimony(V) complex with internally functionalized acetylferroceneoxime: Crystal and molecular structures of [C5H5FeC5H4C(CH3)NO]2SbPh3 and C5H5FeC5H4C(CH3)NOH

Cited by 24 publications

References 15 publications

Study of 2-(piperidine-1-ylmethyl)cyclohexanamine Structure Synthesis Based on Oxime Protected Compounds in Mannich Mechanism

Study of 2-(piperidine-1-ylmethyl)cyclohexanamine Structure Synthesis Based on Oxime Protected Compounds in Mannich Mechanism

Synthesis, Structure and Reactions of Organometallic Derivatives of Oximes

“Cage‐like” Carboxyl Bridged Octaphenyltetraantimony Compounds (SbPh2)4(μ‐O)4(μ‐OH)2(μ‐O2CR)2: Synthesis and Structural Characterization

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“Cage‐like” Carboxyl Bridged Octaphenyltetraantimony Compounds (SbPh₂)₄(μ‐O)₄(μ‐OH)₂(μ‐O₂CR)₂: Synthesis and Structural Characterization