Synthesis, spectroscopic characterization, X-ray analysis and theoretical studies on the spectral features (FT-IR,<sup>1</sup>H-NMR), chemical reactivity, NBO analyses of 2-(4-fluorophenyl)-2-(4-fluorophenylamino)acetonitrile and its docking into IDO enzyme

Brahmachari, Goutam; Kumar, Abhishek; Srivastava, Ambrish Kumar; Gangwar, Shashi Kumar; Misra, Neeraj; Gupta, Vivek K.; Rajnikant,

doi:10.1039/c5ra15797h

Cited by 9 publications

(1 citation statement)

References 61 publications

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“…Additionally, FT-IR spectroscopy validated product acquisition [2-phenyl-2-(phenylamino) acetonitrile] (Figure S10). − …”

Section: Resultsmentioning

confidence: 99%

Synthesis of UiO-66-Pyca-CuO by a Simple and Novel Method: MOF-based Metal Thin Film as Heterogeneous Catalysts for the Synthesis of α-Aminonitriles

Moghadaskhou,

Tadjarodi,

Maleki

2024

ACS Appl. Mater. Interfaces

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Metal−organic frameworks (MOFs), particularly UiO-66-NH 2 , are employed as catalysts in many industrial catalyst applications. As converting catalysts into thin film significantly increases their catalytic properties, we report a general approach to synthesizing MOF thin films (UiO-66-Pyca-CuO). First, functionalization of UiO-66-NH 2 was done with 3-pyridine carboxaldehyde by the postsynthesis method, and then, UiO-66-Pyca was entangled on the surface of copper oxide nanoparticles with a modern strategy (MOF thin film). The morphology and structure of the synthesized UiO-66-Pyca-CuO were determined by using Xray diffraction, Fourier transform infrared, field-emission scanning electron microscopy, energy-dispersive analysis of X-ray, inductively coupled plasma-mass spectrometry, elemental analyses of CHNOS, temperature-programmed desorption of ammonia, Brunauer−Emmett−Teller, and X-ray photoelectron spectroscopy. We studied the catalytic action of the UiO-66-Pyca-CuO thin film in the synthesis of α-aminonitriles via Strecker reaction. Our studies show that this catalysis can be a suitable catalyst in the synthesis of α-aminonitriles because of having advantages such as using the solvent being environmentally friendly, easy separation of the catalyst (only by picking up the MOF thin film from inside the solution), the reaction at room temperature, high yield, and reusability.

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“…Additionally, FT-IR spectroscopy validated product acquisition [2-phenyl-2-(phenylamino) acetonitrile] (Figure S10). − …”

Section: Resultsmentioning

confidence: 99%

Synthesis of UiO-66-Pyca-CuO by a Simple and Novel Method: MOF-based Metal Thin Film as Heterogeneous Catalysts for the Synthesis of α-Aminonitriles

Moghadaskhou,

Tadjarodi,

Maleki

2024

ACS Appl. Mater. Interfaces

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Structural confirmation of biorelevant molecule N-iso-butyl, S-2-nitro-1-phenylethyl dithiocarbamate in gas phase and effect of fluorination

Yadav

Brahmachari

Karmakar

et al. 2021

Chemical Physics Letters

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Polymorphs of 4-isopropylbenzylidine thiophene-2-carbohydrazide: Crystal growth and density functional theory computations

Rajavel

Prasad

Jeyakumar

2017

Journal of Molecular Structure

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Synthesis, spectroscopic characterization, X-ray analysis and theoretical studies on the spectral features (FT-IR,¹H-NMR), chemical reactivity, NBO analyses of 2-(4-fluorophenyl)-2-(4-fluorophenylamino)acetonitrile and its docking into IDO enzyme

Abstract: One-pot green synthesis and combined spectral and theoretical studies of 2-(4-fluorophenyl)-2-(4-fluorophenylamino)acetonitrile along with its X-ray crystallographic properties are described.

Cited by 9 publications

References 61 publications

Synthesis of UiO-66-Pyca-CuO by a Simple and Novel Method: MOF-based Metal Thin Film as Heterogeneous Catalysts for the Synthesis of α-Aminonitriles

Synthesis of UiO-66-Pyca-CuO by a Simple and Novel Method: MOF-based Metal Thin Film as Heterogeneous Catalysts for the Synthesis of α-Aminonitriles

Structural confirmation of biorelevant molecule N-iso-butyl, S-2-nitro-1-phenylethyl dithiocarbamate in gas phase and effect of fluorination

Polymorphs of 4-isopropylbenzylidine thiophene-2-carbohydrazide: Crystal growth and density functional theory computations

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Synthesis, spectroscopic characterization, X-ray analysis and theoretical studies on the spectral features (FT-IR,1H-NMR), chemical reactivity, NBO analyses of 2-(4-fluorophenyl)-2-(4-fluorophenylamino)acetonitrile and its docking into IDO enzyme

Abstract: One-pot green synthesis and combined spectral and theoretical studies of 2-(4-fluorophenyl)-2-(4-fluorophenylamino)acetonitrile along with its X-ray crystallographic properties are described.

Cited by 9 publications

References 61 publications

Synthesis of UiO-66-Pyca-CuO by a Simple and Novel Method: MOF-based Metal Thin Film as Heterogeneous Catalysts for the Synthesis of α-Aminonitriles

Synthesis of UiO-66-Pyca-CuO by a Simple and Novel Method: MOF-based Metal Thin Film as Heterogeneous Catalysts for the Synthesis of α-Aminonitriles

Structural confirmation of biorelevant molecule N-iso-butyl, S-2-nitro-1-phenylethyl dithiocarbamate in gas phase and effect of fluorination

Polymorphs of 4-isopropylbenzylidine thiophene-2-carbohydrazide: Crystal growth and density functional theory computations

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Synthesis, spectroscopic characterization, X-ray analysis and theoretical studies on the spectral features (FT-IR,¹H-NMR), chemical reactivity, NBO analyses of 2-(4-fluorophenyl)-2-(4-fluorophenylamino)acetonitrile and its docking into IDO enzyme