Synthesis, stereochemistry and adsorption studies of new spiranes and polyspiranes containing 1,2‐dithiolane units

Abstract

S SGold Substrate where R 1 , R 2 = H, methyl, phenyl, 1-naphthyl, or R 1 -R 2 = (un)substituted cyclohexylThe synthesis and stereochemistry of a series of new cyclic disulfides containing (poly)spirane 1,2-dithiolane units are reported. Also included is a study of the self-assembled monolayers (SAMs) of these compounds on a gold surface. The characteristics of the resultant SAMs were determined by IR spectroscopy using molecular mechanics calculations.

The Influence of OH Groups in [Fe(CO)3]2[(μ‐ECH2)2C(CH2OH)2] (E = S, Se) Complexes toward the Cathodic Process

“… Synthesis of compound A : ( i ) toluene/acetone, H 3 PO 4 , reflux, 16 h15 ( ii ) EtOH, Na 2 S 2 , reflux, 4 h14 ( iii ) EtOH/H 2 O, HCl, room temperature, 24 h. The detailed procedure of step ( iii ) is presented in the Experimental Section. …”

“…Treatment of Fe 3 (CO) 12 with compound A [14] or B [15] in toluene at 100 °C for one hour followed by column chromatography afforded complexes 1 and 2 in 45 % and 41 % yields, respectively (Scheme 1). We synthesized compound A according to Scheme 2.…”