Synthesis, structure, and magnetic properties of the halide-bridged dimeric complex [(bpmaL1)Fe(μ-Cl)Cl]2

Yang, Minkyu; Kim, Eun‐Hee; Jeong, Jong Hwa; Min, Kil Sik; Lee, Hyosun

doi:10.1016/j.ica.2012.09.010

Cited by 7 publications

(1 citation statement)

References 53 publications

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“…The polynuclear transition metal complexes have relatively strong intra or inter molecular metal–metal interactions. Based on their chemical properties, many polynuclear transition metal complexes have potential applications in various fields, such as catalysts for organic reactions and biological systems and supramolecular and materials chemistry based on their magnetic properties . Specifically, dinuclear or polynuclear copper(II) complexes have long metal–metal distances, and their interaction shows interesting behavior, such as magnetic properties .…”

Section: Introductionmentioning

confidence: 99%

Copper(II) Complexes Containing N,N′‐Bidentate N‐(Pyridin‐2‐ylmethyl)aniline and Its Derivatives: Synthesis, Structure and Magnetic Property

Ahn

Lee

2015

Bulletin Korean Chem Soc

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New Cu(II) complexes, dinuclear [CuLb(μ‐Cl)Cl]2 and monomeric [CuLcCl2], along with polynuclear [CuLaCl2]n for comparison, were prepared and characterized using X‐ray crystallography. Variable‐temperature (2−300 K) magnetic susceptibility (χ) data of [CuLaCl2]n and [CuLb(μ‐Cl)Cl]2 showed weak antiferromagnetic interactions through the bridged chlorido groups within the polymeric and dimeric units, respectively.

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Section: Introductionmentioning

confidence: 99%

Copper(II) Complexes Containing N,N′‐Bidentate N‐(Pyridin‐2‐ylmethyl)aniline and Its Derivatives: Synthesis, Structure and Magnetic Property

Ahn

Lee

2015

Bulletin Korean Chem Soc

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Palladium(II) Complexes with N,N′‐Bidentate N‐Methyl‐N‐(pyridin‐2‐ylmethyl)aniline and its Derivatives: Synthesis, Characterization, and Methyl Methacrylate Polymerization

Kim

Song

Lee

et al. 2015

Bulletin Korean Chem Soc

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The N,N′‐bidentate [( N , N ′) PdCl2 ] complexes [i.e., [ L n PdCl2 ] (L n = L1–L5 )] were synthesized by the reaction of [Pd( CH3CN ) 2Cl2 ] with N‐methyl‐N‐(pyridin‐2‐ylmethyl)aniline ( L1 ) and its derivatives ( L2–L5 ) in ethanol. The molecular structures of [ L n PdCl2 ] (L n = L1–L3 ) were characterized using X‐ray crystallography, which showed that the Pd atom in the Pd(II) complexes had a square planar geometry involving two nitrogen atoms of N,N′‐bidentate and two chlorido ligands. The complexes [ L n PdCl2 ] (L n = L1–L5 ) were investigated for methyl methacrylate (MMA) polymerization in the presence of modified methylaluminoxane (MMAO) at 60 °C. Specifically, complex [ L1PdCl2 ] showed moderate catalytic activity toward MMA polymerization with an activity of 3.03 × 104 g poly(methylmethacrylate) (PMMA)/mol Pd·h and PMMA syndiotacticity (characterized by 1H NMR spectroscopy) of ~0.68.

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Synthesis, structures and reactivity of cobalt(II) complexes supported by N,N,N′,N″-tetradentate N′-substituted bis((1H-pyrazol-1-yl)methyl)amine

Seo

Lee

Kim

et al. 2019

Inorganica Chimica Acta

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Synthesis, structure, and magnetic properties of the halide-bridged dimeric complex [(bpmaL1)Fe(μ-Cl)Cl]2

Cited by 7 publications

References 53 publications

Copper(II) Complexes Containing N,N′‐Bidentate N‐(Pyridin‐2‐ylmethyl)aniline and Its Derivatives: Synthesis, Structure and Magnetic Property

Copper(II) Complexes Containing N,N′‐Bidentate N‐(Pyridin‐2‐ylmethyl)aniline and Its Derivatives: Synthesis, Structure and Magnetic Property

Palladium(II) Complexes with N,N′‐Bidentate N‐Methyl‐N‐(pyridin‐2‐ylmethyl)aniline and its Derivatives: Synthesis, Characterization, and Methyl Methacrylate Polymerization

Synthesis, structures and reactivity of cobalt(II) complexes supported by N,N,N′,N″-tetradentate N′-substituted bis((1H-pyrazol-1-yl)methyl)amine

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