“…Keeping in mind the structure–property relationship, this approach paves the way to the design of materials that are interesting from both fundamental research and industrial applications perspectives. They can be formed from numerous organic 4,9,21–24 and inorganic 21,25,26 cations, halide anions, and their mixtures, 21,27–29 leading to technologically promising optical, 21,30 physico-chemical, 31 and electrical 10,30 properties. The structure–property relationship is most prominent in the case of quasi low-dimensional hybrid organometal halides with aromatic organic cations.…”