Synthesis, structure, and thermal decomposition of a novel one-dimensional chain complex of manganese(II) with 2,2-diphenic acid and 1,10-phenanthroline

The title compound, [Mn2(C14H8O4)2(C10H8N2)2(H2O)5]·4H2O, has been obtained under hydrothermal conditions. In the asymmetric unit, there are two crystallographically distinct MnII ions, bridged by a dpa2− ligand (H2dpa = diphenic acid), which are sixfold coordinated by four O atoms and two N atoms. The O atoms coordinated to one Mn atom are from three water molecules and one dpa2− ligand, while those coordinated to the other Mn atom are from two water molecules and two dpa2− ligands. In the crystal structure, centrosymmetric dimers are formed via a pair of intermolecular O—H...O hydrogen bonds.

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Pentaaqua-1κ²O,2κ³O-bis(2,2′-bipyridine)-1κ²N,N′;2κ²N,N′-μ-biphenyl-2,2′-dicarboxylato-1:2κ²O:O′-biphenyl-2,2′-dicarboxylato-1κO-dimanganese(II) tetrahydrate

Fang

Zhao

2007

Acta Cryst E

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catena-Poly[diaquatris(μ₃-biphenyl-2,2′-dicarboxylato)dierbium(III)]

2007

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The title rare earth metal coordination polymer, [Er2(C14H8O4)3(H2O)2]n, has been synthesized through a hydrothermal reaction and characterized by thermogravimetric analysis and single‐crystal X‐ray diffraction. The ErIII ions both lie on crystallographic twofold rotation axes. There are one and a half organic ligands in the asymmetric unit. Both Er ions are coordinated by eight O atoms. Whereas one is bonded only to organic ligands, the other is also coordinated by two water molecules.

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Synthesis, structure, and thermal decomposition of a novel one-dimensional chain complex of manganese(II) with 2,2-diphenic acid and 1,10-phenanthroline

Cited by 2 publications

References 9 publications

Pentaaqua-1κ²O,2κ³O-bis(2,2′-bipyridine)-1κ²N,N′;2κ²N,N′-μ-biphenyl-2,2′-dicarboxylato-1:2κ²O:O′-biphenyl-2,2′-dicarboxylato-1κO-dimanganese(II) tetrahydrate

Pentaaqua-1κ²O,2κ³O-bis(2,2′-bipyridine)-1κ²N,N′;2κ²N,N′-μ-biphenyl-2,2′-dicarboxylato-1:2κ²O:O′-biphenyl-2,2′-dicarboxylato-1κO-dimanganese(II) tetrahydrate

catena-Poly[diaquatris(μ₃-biphenyl-2,2′-dicarboxylato)dierbium(III)]

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Synthesis, structure, and thermal decomposition of a novel one-dimensional chain complex of manganese(II) with 2,2-diphenic acid and 1,10-phenanthroline

Cited by 2 publications

References 9 publications

Pentaaqua-1κ2O,2κ3O-bis(2,2′-bipyridine)-1κ2N,N′;2κ2N,N′-μ-biphenyl-2,2′-dicarboxylato-1:2κ2O:O′-biphenyl-2,2′-dicarboxylato-1κO-dimanganese(II) tetrahydrate

Pentaaqua-1κ2O,2κ3O-bis(2,2′-bipyridine)-1κ2N,N′;2κ2N,N′-μ-biphenyl-2,2′-dicarboxylato-1:2κ2O:O′-biphenyl-2,2′-dicarboxylato-1κO-dimanganese(II) tetrahydrate

catena-Poly[diaquatris(μ3-biphenyl-2,2′-dicarboxylato)dierbium(III)]

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Pentaaqua-1κ²O,2κ³O-bis(2,2′-bipyridine)-1κ²N,N′;2κ²N,N′-μ-biphenyl-2,2′-dicarboxylato-1:2κ²O:O′-biphenyl-2,2′-dicarboxylato-1κO-dimanganese(II) tetrahydrate

Pentaaqua-1κ²O,2κ³O-bis(2,2′-bipyridine)-1κ²N,N′;2κ²N,N′-μ-biphenyl-2,2′-dicarboxylato-1:2κ²O:O′-biphenyl-2,2′-dicarboxylato-1κO-dimanganese(II) tetrahydrate

catena-Poly[diaquatris(μ₃-biphenyl-2,2′-dicarboxylato)dierbium(III)]