1990
DOI: 10.1016/0022-4596(90)90242-p
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Synthesis, structure, electric, and magnetic properties of CaNiN

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Cited by 87 publications
(63 citation statements)
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“…CaNiN [18] (see Fig. 1) is an isotype of the YCoC type structure [19] and also isotype to SrLiN [20].…”
Section: Crystal Structures and Sample Preparationmentioning
confidence: 97%
See 1 more Smart Citation
“…CaNiN [18] (see Fig. 1) is an isotype of the YCoC type structure [19] and also isotype to SrLiN [20].…”
Section: Crystal Structures and Sample Preparationmentioning
confidence: 97%
“…For q exp • we calculate a value of 0.0(2.0) • 10 21 Vm -2 . From magnetic susceptibility measurements [18] a change from paramagnetic to antiferromagnetic behavior at 7 K was concluded. The lack of a magnetic hyperfine field in the Möss-bauer spectrum of CaNiN may be explained by rapid fluctuations of the spin orientation, too fast for the Mössbauer time window.…”
Section: Baniomentioning
confidence: 99%
“…In an e!ort to discover noncuprate superconductors, late transition metal nitrides were synthesized and their electronic and magnetic properties characterized (2). An emphasis was placed on nickel nitrides for several reasons (3): Ni> has an electronic con"guration (d) similar to Cu> in cuprate superconductors, Ni}N bonding may be similar to Cu}O bonding (combined cation and anion character at the Fermi level), and metallic conductivity was previously observed in CaNiN (4).…”
Section: Introductionmentioning
confidence: 96%
“…CaNiN (P42/mmc, a = 3.5809(2) Å, c = 7.0096(3) Å) was discovered in 1990 by DiSalvo and found to contain [NiN ⁄ ] linear chains [68]. These form planes of parallel chains, which are stacked along the c-axis.…”
Section: Nitrides Containing Infinite Linear Chainsmentioning
confidence: 99%