Synthesis, structure refinement and thermal behavior of HEuP2O7⋅4H2O

Anna-Rabah, Zohra; Chehimi-Moumen, Fathia; Hassen‐Chehimi, D. Ben; Trabelsi‐Ayadi, Malika

doi:10.1016/j.solidstatesciences.2006.01.018

Cited by 9 publications

(2 citation statements)

References 16 publications

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“…Similarly, the coordination environment of other rare-earth compounds with the same coordination number are also described as distorted bicapped trigonal prismatic [55][56][57][58][59] or distorted square antiprismatic. [39,42,[60][61][62][63][64][65][66][67][68][69][70] The interatomic distances and angles for 1-4 are listed in Tables 2 and 3 [39] In a distorted square antiprism in the form of an ideal snub disphenoid, the angles are between 65°and 145°with an average of 100°. In 1-3, all of the values are close to 100°.…”

Section: Structuresmentioning

confidence: 99%

Rare‐Earth Tetracyanidoborate Salts – Structural Features and Properties Including Luminescence of [RE(H₂O)₈][B(CN)₄]₃·nH₂O and [RE(H₂O)₇{κ¹N‐B(CN)₄}][B(CN)₄]₂ (RE = Y, Tb, Dy, Ho, Er, Tm, Yb, Lu; n ≤ 3)

et al. 2016

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Section: Structuresmentioning

confidence: 99%

Rare‐Earth Tetracyanidoborate Salts – Structural Features and Properties Including Luminescence of [RE(H₂O)₈][B(CN)₄]₃·nH₂O and [RE(H₂O)₇{κ¹N‐B(CN)₄}][B(CN)₄]₂ (RE = Y, Tb, Dy, Ho, Er, Tm, Yb, Lu; n ≤ 3)

et al. 2016

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“…The title compound is isostructural with other compounds of formula type REHP 2 O 7 . 4H 2 O, RE = Sm (Chehimi-Moumen et al, 2002), Gd (Hraiech et al, 2005), and Eu (Anna-Rabah et al, 2006).…”

Section: Sup-1mentioning

confidence: 99%

Terbium(III) hydrogendiphosphate(V) tetrahydrate

et al. 2008

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The Tb atom of the title compound, TbHP2O7·4H2O, is coordinated by the O atoms of three symmetrically independent water molecules and by five O atoms belonging to HP2O7 − groups. The TbO8 polyhedra are interconnected by the diphospate anions, forming a three-dimensional network which is additionally stabilized by O—H⋯O hydrogen bonding between water molecules and O atoms of the HP2O7 − anions. Uncoordinated water molecules are situated in channels and are connected via hydrogen bonds with the framework.

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Synthesis, Structure Refinement and Thermal Behavior of HEuP₂O₇×4H₂O.

Anna-Rabah¹,

Chehimi-Moumen²,

Hassen‐Chehimi³

et al. 2006

ChemInform

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Structure D 2000 Synthesis, Structure Refinement and Thermal Behavior of HEuP 2 O 7 ·4H 2 O. -Colorless prismatic crystals of the new title compound are prepared at room temperature from aqueous solutions of EuCl3 and H4P2O7. HEuP2O7·4H2O crystallizes in the monoclinic space group P21/n with Z = 4 (single crystal XRD). The crystal structure consists of corrugated layers of [HP2 ] groups alternating with layers of the Eu 3+ cations. Dehydration of the compound takes place between 361 and 1223 K to give a mixture of Eu4(P2O7)3 and Eu(PO3)3. -(ANNA-RABAH, Z.; CHEHIMI-MOUMEN*, F.; HASSEN-CHEHIMI, D. B.; TRABELSI-AYADI, M.; Solid State Sci. 8 (2006) 8, 932-939; Lab. Physico-Chim. Miner., Fac. Sci. Bizerte, 7021 Zarzouna, Tunisia; Eng.) -W. Pewestorf 43-006 O 3 -7

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Synthesis, structure refinement and thermal behavior of HEuP2O7⋅4H2O

Cited by 9 publications

References 16 publications

Rare‐Earth Tetracyanidoborate Salts – Structural Features and Properties Including Luminescence of [RE(H₂O)₈][B(CN)₄]₃·nH₂O and [RE(H₂O)₇{κ¹N‐B(CN)₄}][B(CN)₄]₂ (RE = Y, Tb, Dy, Ho, Er, Tm, Yb, Lu; n ≤ 3)

Rare‐Earth Tetracyanidoborate Salts – Structural Features and Properties Including Luminescence of [RE(H₂O)₈][B(CN)₄]₃·nH₂O and [RE(H₂O)₇{κ¹N‐B(CN)₄}][B(CN)₄]₂ (RE = Y, Tb, Dy, Ho, Er, Tm, Yb, Lu; n ≤ 3)

Terbium(III) hydrogendiphosphate(V) tetrahydrate

Synthesis, Structure Refinement and Thermal Behavior of HEuP₂O₇×4H₂O.

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Synthesis, structure refinement and thermal behavior of HEuP2O7⋅4H2O

Cited by 9 publications

References 16 publications

Rare‐Earth Tetracyanidoborate Salts – Structural Features and Properties Including Luminescence of [RE­(H2O)8][B(CN)4]3·nH2O and [RE­(H2O)7{κ1N‐B(CN)4}][B(CN)4]2 (RE = Y, Tb, Dy, Ho, Er, Tm, Yb, Lu; n ≤ 3)

Rare‐Earth Tetracyanidoborate Salts – Structural Features and Properties Including Luminescence of [RE­(H2O)8][B(CN)4]3·nH2O and [RE­(H2O)7{κ1N‐B(CN)4}][B(CN)4]2 (RE = Y, Tb, Dy, Ho, Er, Tm, Yb, Lu; n ≤ 3)

Terbium(III) hydrogendiphosphate(V) tetrahydrate