Chem. Commun.
 2024
DOI: 10.1039/d4cc00922c
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Synthetic, structural and reactivity studies of a boryl-ethynyl Silylene

Wenhao Chen,
Haisheng Hu,
Jie Feng
et al.

Abstract: The salt metathesis of boryl-ethynyl lithium salt {[(HCDipN)2]B-CC-Li} with monochlorosilylene [LSi(:)Cl; L = PhC(NtBu)2] produced an isolable boryl-ethynyl silylene {1; [(HCDipN)2]B-C≡C-Si(L)}. The Si(II) center in 1 possesses a nonbonding lone...

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