2020
DOI: 10.1002/jssc.202000269
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Systematic evaluation and optimization of high‐performance liquid chromatography separation of polyoxins

Abstract: The chromatographic behavior of a kind of nucleoside peptides, polyoxins, was investigated in this study. Molecular simulation technique was used to elucidate the temperature‐dependent peak sharpening of polyoxins. There was a relatively small energy barrier between the global minimum conformer and the local minimum conformer of polyoxin A and the high temperature helped to quickly cross the energy barrier and accelerate the conformational transformation for getting the global minimum, so that stationary phase… Show more

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