This chapter reviews recent developments on the analysis of the impact of clean technologies on the outcome of transboundary pollution games and on the size of stable environmental agreements. It is shown that given a fall in the emission-output ratio, countries may respond by increasing their emissions resulting in an increase in pollution stock and decrease in welfare. This rebound e¤ect happens when the damage and/or the initial stock of pollution are relatively large and when the natural rate of decay of pollution is relatively small. This implies that clean technologies may not be a substitute for cooperation on mitigation. The impact of cleaner technologies on the success of environmental agreements is then analyzed when countries are farsighted. In the case of three groups of countries, the grand coalition may be destabilized by the implementation of cleaner technologies, ultimately resulting in higher global emissions and lower global welfare. In the case of more than three countries, implementing cleaner technologies may result in a discrete jump, either upward or downward, of the largest stable coalition size and welfare.