“…The sample mass was between 120 and 300 ng, and was estimated by comparing the measured heatcapacity increment on heating a fully amorphous sample at the glass transition temperature T g in units of J/K with the expected mass-specific heat-capacity increment of 0.51 J/(g K) [15]. Further details about the instrument/sensor are reported in [13,44,45].…”
“…The sample mass was between 120 and 300 ng, and was estimated by comparing the measured heatcapacity increment on heating a fully amorphous sample at the glass transition temperature T g in units of J/K with the expected mass-specific heat-capacity increment of 0.51 J/(g K) [15]. Further details about the instrument/sensor are reported in [13,44,45].…”
“…For both of the geometries, theˇdependence is well fit by straight lines in agreement with the prediction of the shifts of Eqs. (5) and (6). The thick straight line in Fig.…”
Section: Thin Polymer Film (L = 32 M)mentioning
confidence: 92%
“…The shift of T PE peak withˇrepresents an apparent superheating with the contributions of both of the true superheating of the melting kinetics and the thermal lags typically expressed as Eq. (6).…”
Section: Dependences On Pe Film Mass and Thicknessmentioning
confidence: 99%
“…Fast-scan nanocalorimetry [1][2][3][4][5][6][7] enables us to apply fast heating at the rates, ca. 10 4 K s −1 , several orders faster than the rates applicable with conventional calorimetry.…”
“…The Flash DSC1 was connected to a Huber TC 100 intracooler.Indium, zinc, tin and ademantanewere used for temperature calibration of the Flash DSC1 [15]. Flash Liquid DSC1makes use of sensors based on Micro-Electro-MechanicalSystems technology [16].…”
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