Temperature-induced dielectric and electrical behavior of Cs/HPC-copper vanadate nanocomposites

Abstract

This study investigates the effects of temperature exposure on the dielectric and electrical properties of Cs/HPC-copper vanadate nanocomposites. The results indicate a direct correlation between the increase in polymer surface roughness and the amount of incorporated copper vanadate nanoparticles. The real dielectric constant and imaginary dielectric constant exhibited a notable increase at lower frequencies, which was attributed to interfacial polarization. At higher frequencies, the decrease was due to space charge polarization. The incorporation of copper vanadate nanoparticles resulted in a significant enhancement of both the real dielectric constant and imaginary dielectric constant highlighting the crucial role of these nanoparticles in the electrical properties of the nanocomposites. The impedance (Z') and impedance (Z") measurements indicate a decrease in Z' with increasing frequency and temperature, suggesting enhanced ionic conductivity and interfacial polarization. The Cole-Cole plots reveal that the dielectric relaxation process in the Cs/HPC-copper vanadate nanoparticles (NPs) follow the non-Debye model. The results provide insights into the charge-transport mechanisms in these nanocomposites and highlight the importance of temperature in controlling their electrical properties.