2017
DOI: 10.1103/physrevb.95.024101
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Temperature-induced valence instability in the charge-transfer crystal TMB-TCNQ

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Cited by 16 publications
(59 citation statements)
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“…Despite the many similarities with TTF-CA, and the convenient high temperature of the transition, no further investigation has been performed, except for a study on the thermal hysteresis, where it was shown that the crystals break at the transition [47]. A recent reinvestigation [19], that we summarize here, has helped to clarify some issues and to better characterize the phase transition and its mechanism. Figure 14 compares the polarized IR absorption spectra above and below the phase transition in the spectral regions of interest.…”
Section: Tmb-tcnqmentioning
confidence: 99%
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“…Despite the many similarities with TTF-CA, and the convenient high temperature of the transition, no further investigation has been performed, except for a study on the thermal hysteresis, where it was shown that the crystals break at the transition [47]. A recent reinvestigation [19], that we summarize here, has helped to clarify some issues and to better characterize the phase transition and its mechanism. Figure 14 compares the polarized IR absorption spectra above and below the phase transition in the spectral regions of interest.…”
Section: Tmb-tcnqmentioning
confidence: 99%
“…IR absorption spectra of TMB-TCNQ polarized perpendicularly and parallel to the stack axis, above (HT) and (LT) below the phase transition. From [19]. Figure 14 shows that the low-temperature TMB-TCNQ IR spectrum polarized along the stack axis (red trace in right panel of Figure 14) is dominated by a set of new, very strong bands, clearly due to e-mv coupling.…”
Section: Tmb-tcnqmentioning
confidence: 99%
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