2024
DOI: 10.1021/acs.joc.4c01353
|View full text |Cite
|
Sign up to set email alerts
|

TEMPO as Hydrogen Atom Transfer Catalyst in Enhancing Iminyl Radical Cyclization of O-Acetyl Oxime toward Phenanthridines and Isoquinolines

Zi-Xuan Liu,
Hao-Yuan Li,
Shigang Shen
et al.

Abstract: Herein, we present a strategy for promoting the cyclization of ortho-aryl or ortho alkenyl arylketone oxime ethers C− N bonds using TEMPO as a direct hydrogen atom transfer (HAT) catalyst. The reaction employs a green solvent and requires no introduction of metal additives. It only needs catalytic amount of TEMPO to drive the reaction. Gram-scale reaction yields the corresponding products with satisfactory yields, providing a novel and efficient method for the synthesis of phenanthridine and isoquinoline deriv… Show more

Help me understand this report

Search citation statements

Order By: Relevance

Paper Sections

Select...

Citation Types

0
0
0

Publication Types

Select...

Relationship

0
0

Authors

Journals

citations
Cited by 0 publications
references
References 45 publications
0
0
0
Order By: Relevance

No citations

Set email alert for when this publication receives citations?