Ternary charge transfer complexes. V. Complexes with thiazyl salts

Abstract

Charge transfer complexes NS'MFn-'arene, where M = B, tz = 4; M = P, As, or Sb, n = 6; and arene is hexamethylbenzene, mesitylene, napthalene, or 9,lO-dimethylanthracene, have been prepared and characterized. The reaction of NS+MF6-(M = As or Sb) with highly oriented pyrolytic graphite results in graphite intercalated only with the metal fluoride anions.SYDNEY BROWNSTEIN and BRENDA LOUIE. Can. J. Chem. 65, 1361(1987.On a prepare et caractCrisC les complexes de transfert de charge MS'MFn-.arkne dans lesquels M = B, n = 4; M = P, As ou Sb, n = 6 et arkne = hexamCthylbenzkne, mesitylkne, naphtalkne ou dimethyl-9,10 anthrackne. La reaction des composCs MS+MF6-(M = As ou Sb) avec du graphite pyrolytique hautement orient6 conduit a des graphites qui sont uniquement intercales par des anions de fluorures metalliques.[Traduit par la revue]