“…Solution-processed organic solar cells (OSCs), with their unique features of low weight, flexibility, semitransparency, and inexpensive manufacturing techniques, enable the development of the most promising energy technology for applications such as portable electronics, wearable devices, and building-integrated photovoltaics. − The power conversion efficiencies (PCEs) of the state-of-the-art OSCs have been boosted to over 19% in recent years due to the development of novel conjugated wide band gap polymer donors and narrow band gap nonfullerene acceptors (NFAs) for the active layer. − In contrast to the outstanding achievements on absorbing layer systems, research on transport layers is far behind. Besides, the long-term sustainability of OSCs remains a challenge. ,, The current research scenario is focused on addressing these challenges to improve the performance and stability of OSCs. − With regards to the electron transport layer (ETL) materials, such as conjugated and nonconjugated polymers, − organic small molecules, , and transition metal oxides, , interface engineering for the manipulation of the internal built-in potential using novel molecules and 2D materials − has exhibited efficient performance in OSCs due to their excellent optical and electronic properties.…”