Terpenes as natural building blocks for the synthesis of hierarchically porous polymers: bio-based polyHIPEs with high surface areas

Kramer, Stanko; Skušek, Nika; Krajnc, Peter

doi:10.1039/d2py01566h

Polym. Chem.

2023

DOI: 10.1039/d2py01566h

|View full text |Cite

Terpenes as natural building blocks for the synthesis of hierarchically porous polymers: bio-based polyHIPEs with high surface areas

Stanko Kramer

Nika Skušek

Peter Krajnc

Abstract: PolyHIPEs are hierarchically porous polymers which are generally synthesised from synthetic constituents produced from fossil fuels. The need to produce sustainable materials makes terpenes great candidates for the preparation of...

Help me understand this report

Search citation statements

Order By: Relevance

Paper Sections

Select...

Citation Types

Supporting

Mentioning

Contrasting

Year Published

2023

2024

Publication Types

Select...

Article4

Relationship

Self Cite0

Independent4

Authors

Journals

Cited by 4 publications

References 37 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

Influence of crosslinker on the properties of terpene‐based poly(high internal phase emulsion)s

Beyaz,

Kramer,

Kekevi

et al. 2024

Polymer International

View full text Add to dashboard Cite

Poly(high internal phase emulsion)s (polyHIPEs) are an important class of porous polymeric materials, where HIPEs are used to create hierarchical open porosity. In order to synthesize more sustainable and greener polymer materials, bio‐derived terpene‐based polyHIPEs are becoming increasingly important. Herein, polyHIPEs were synthesized by free radical copolymerization crosslinking of β‐myrcene with flexible poly(ethylene glycol dimethacrylate) or ethylene glycol dimethacrylate in water‐in‐oil HIPEs. The influence of using a flexible oligomeric crosslinker on pore morphology and mechanical properties of the resulting terpene‐based polyHIPEs was investigated. Morphological and mechanical characterization of the terpene‐based polyHIPEs reveals that using crosslinkers with varied flexibility significantly influences pore morphology and mechanical strength. In addition, altering the amount of crosslinker in the HIPE template has proved to be an important parameter in the final material properties. While the structure of the crosslinker has a less pronounced influence on the polyHIPE morphology, mechanical properties are significantly affected due to the difference in the resulting polymer architecture and free volume. © 2024 The Author(s). Polymer International published by John Wiley & Sons Ltd on behalf of Society of Chemical Industry.

show abstract

Influence of crosslinker on the properties of terpene‐based poly(high internal phase emulsion)s

Beyaz,

Kramer,

Kekevi

et al. 2024

Polymer International

View full text Add to dashboard Cite

show abstract

Poly(HIPEs) from terpenoid-derived acrylates

Kramer,

Slavič,

Krajnc

2023

Colloid Polym Sci

View full text Add to dashboard Cite

Preparation and characterization of palmitic acid/polymer composite phase change materials supported with cross-linked poly(limonene-co-ethylene glycol dimethacrylate) copolymers for low-temperature thermal applications

Kekevi,

Mert,

Mert

et al. 2024

Reactive and Functional Polymers

View full text Add to dashboard Cite

scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.

Contact Info

customersupport@researchsolutions.com

10624 S. Eastern Ave., Ste. A-614

Henderson, NV 89052, USA

This site is protected by reCAPTCHA and the Google Privacy Policy and Terms of Service apply.

Blog Terms and Conditions API Terms Privacy Policy Contact Cookie Preferences Do Not Sell or Share My Personal Information

Made with 💙 for researchers

Part of the Research Solutions Family.

Terpenes as natural building blocks for the synthesis of hierarchically porous polymers: bio-based polyHIPEs with high surface areas

Abstract: PolyHIPEs are hierarchically porous polymers which are generally synthesised from synthetic constituents produced from fossil fuels. The need to produce sustainable materials makes terpenes great candidates for the preparation of...

Cited by 4 publications

References 37 publications

Influence of crosslinker on the properties of terpene‐based poly(high internal phase emulsion)s

Influence of crosslinker on the properties of terpene‐based poly(high internal phase emulsion)s

Poly(HIPEs) from terpenoid-derived acrylates

Preparation and characterization of palmitic acid/polymer composite phase change materials supported with cross-linked poly(limonene-co-ethylene glycol dimethacrylate) copolymers for low-temperature thermal applications

Contact Info

Product

Resources

About