Tetrabutylammonium Bifluoride as an Efficient Activating Agent for Copper-Catalyzed Vinylsilane Cross-Coupling Reactions

The urgency of improving the efficiency of known methods and developing new ones for the synthesis of unsaturated silanes is caused by the need to obtain useful compounds, including biologically active ones, on their basis. This review considers methods for the preparation of unsaturated silanes, their transformations and prospects for their use as precursors in organic and organoelement synthesis. A large number of substituted organosilicon products are given, including those capable of further functionalization and the formation of heterocycles, including silaheterocycles. <br> The bibliography includes 205 references.

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Tetrabutylammonium Bifluoride as an Efficient Activating Agent for Copper-Catalyzed Vinylsilane Cross-Coupling Reactions

Abstract: Vinylsilanes are versatile and efficient nucleophiles in cross-coupling reactions. Herein is described the use of tetrabutylammonium bifluoride as a mild, cheap and scalable activating agent in several copper-catalyzed vinylsilane cross-couplings.

Cited by 2 publications

References 6 publications

Copper-catalyzed Cross-coupling Reaction between Aryl(trialkyl)silanes and Alkyl Halides

Copper-catalyzed Cross-coupling Reaction between Aryl(trialkyl)silanes and Alkyl Halides

Unsaturated organosilanes: synthesis, transformations and applications

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