Tetrapyrrolic Macrocycles: Synthesis, Functionalization and Applications 2018

Moura, Nuno M. M.; Faustino, Maria A. F.; Neves, Maria G. P. M. S.

doi:10.3390/molecules25030433

Cited by 2 publications

(1 citation statement)

References 13 publications

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“…Porphyrins and their derivatives play an important role in chemistry and biology; they participate in light-harvesting, oxygen transport and catalytic transformations [239][240][241][242]. Ligand based on porphyrins benefit from their rigid scaffold, photophysical properties and allow to obtain a wide range of coordination polymers with diverse luminescent properties [243][244][245].…”

Section: Porphyrin Derivativesmentioning

confidence: 99%

Coordination Polymers Based on Highly Emissive Ligands: Synthesis and Functional Properties

et al. 2020

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Coordination polymers are constructed from metal ions and bridging ligands, linking them into solid-state structures extending in one (1D), two (2D) or three dimensions (3D). Two- and three-dimensional coordination polymers with potential voids are often referred to as metal-organic frameworks (MOFs) or porous coordination polymers. Luminescence is an important property of coordination polymers, often playing a key role in their applications. Photophysical properties of the coordination polymers can be associated with intraligand, metal-centered, guest-centered, metal-to-ligand and ligand-to-metal electron transitions. In recent years, a rapid growth of publications devoted to luminescent or fluorescent coordination polymers can be observed. In this review the use of fluorescent ligands, namely, 4,4′-stilbenedicarboxylic acid, 1,3,4-oxadiazole, thiazole, 2,1,3-benzothiadiazole, terpyridine and carbazole derivatives, naphthalene diimides, 4,4′,4′′-nitrilotribenzoic acid, ruthenium(II) and iridium(III) complexes, boron-dipyrromethene (BODIPY) derivatives, porphyrins, for the construction of coordination polymers are surveyed. Applications of such coordination polymers based on their photophysical properties will be discussed. The review covers the literature published before April 2020.

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Section: Porphyrin Derivativesmentioning

confidence: 99%

Coordination Polymers Based on Highly Emissive Ligands: Synthesis and Functional Properties

et al. 2020

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Porphyrin-based supramolecular assemblies and their applications in NLO and PDT

Mrinalini

Naresh

Prasanthkumar

et al. 2021

J. Porphyrins Phthalocyanines

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Tetrapyrrolic systems largely inspired by nature have attracted much attention in organic electronics and biomedical applications owing to their planar structure and extended [Formula: see text]-conjugated double bonds. As a result, delocalization of [Formula: see text]-electron cloud leads the excellent optical absorption and fluorescent properties. Nonetheless, the utilization of non-covalent interactions result in the self-assembled nanostructures providing applications in bioimaging and electronics. In this review, it is demonstrated that the recent reports on the self-assembly in tetrapyrrolic systems via supramolecular interactions lead to well-defined nanoarchitectures. Moreover, the importance of porphyrin based derivatives in nanoelectronics and chemotherapeutic applications is reported. Therefore, the inclination of tetrapyrroles towards the design and development of novel supramolecular nanostructures are considered the hallmark for nanorobotics, shape memory polymers and bionic arms.

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Tetrapyrrolic Macrocycles: Synthesis, Functionalization and Applications 2018

Cited by 2 publications

References 13 publications

Coordination Polymers Based on Highly Emissive Ligands: Synthesis and Functional Properties

Coordination Polymers Based on Highly Emissive Ligands: Synthesis and Functional Properties

Porphyrin-based supramolecular assemblies and their applications in NLO and PDT

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