Org. Chem. Front.
 2025
DOI: 10.1039/d4qo01890g
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Tf2O-induced selective 1,3-transposition/cyclization of ynones in DMF

Hui-Lin Lan,
Wenting Liu,
Wen Liu
et al.

Abstract: A chemo and regio-selective system for activating C=O and S=O bonds under transition metal-free conditions is described. Thus, a Tf2O-mediated 1,3-transposition of ynones in DMF has been developed, providing a...

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