2014
DOI: 10.1055/s-0034-1378563
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The chiro-Inositols and Related Cyclitols as Chiral Monomers for Polymerization: Expansion of a Family of Chiral Polymers

Abstract: Three different synthetic approaches to three different classes of oligomeric and polymeric inositol and inositol-like derivatives are presented: Grubbs cross-metathesis polymerization, Lewis acid catalyzed epoxide opening, and head-to-tail Diels-Alder polymerization. All three approaches lead to the formation of oligomers and polymers. The oligomers/polymers formed range from three (low-molecular-weight fraction of Diels-Alder polymerization) to 60 (Lewis acid catalyzed polymerization) repeats of inositol or … Show more

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Cited by 4 publications
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