The comparative studies on the magnetic relaxation behaviour of the axially-elongated pentagonal-bipyramidal dysprosium and erbium ions in similar one-dimensional chain structures

Abstract

A family of cyano-bridged 3d−4f 1D chain compounds, {RE[TM(CN)6(2-PNO)5]}·(H2O)4 {RE = YIII, TM = [FeIII]LS (1); RE = DyIII, TM = CoIII (3); RE = ErIII, TM = [FeIII]LS (4),...

Single molecule magnet features in luminescent lanthanide coordination polymers with heptacoordinate Dy/Yb(iii) ions as nodes

“…34 Although several Ln coordination polymers with SMM behavior have been reported before, 34–52 Ln coordination polymers with SMM behavior constructed from seven-coordinated Ln ions are still scarce. 53–57…”

Self-assembly of octanuclear Ln(iii)-based clusters: their large magnetocaloric effects and highly efficient conversion of CO2

“…The Cole–Cole curves are fitted by a generalized Debye model, 92 yielding α values in the range of 0.08–0.51, which suggested a relatively wide distribution of the relaxation time for cluster 2 . 93–102…”

Two-Dimensional Metal Azides Constructed by a Ln@Co6Cluster and Disordered Co3(N3)11Units

“…In recent years, molecule-based magnetic materials have attracted extensive attention due to their important properties and potential application prospects. − Among them, the 3d–4f heterometallic complexes exhibit various structures and excellent magnetic properties which are significant in both crystal engineering and magnetism investigations. − Many 3d–4f complexes with finite nuclear clusters and infinite structure chains, layers, and networks have been synthesized with different strategies. ,,− In the high-nuclear clusters or coordination polymers, it is found that some 3d–4f clusters have small nuclearity as building blocks, which are connected to each other through the 4f ions. ,− However, the connections that are not conducive to transfer magnetic interactions for 4f electrons are inner shell electrons and are not coupled effectively with other spin carriers . To avoid the above problems, small 3d–4f clusters should be connected by a “magnetic bridge” through the 3d ions.…”