“…Na 0.5 Bi 0.5 TiO 3 is a lead-free ferroelectric that has served as a base for extensively developing piezoelectric ceramics [4,5]. Among doping ions, divalent cations, such as Mg 2þ [6], Ca 2þ [7], Sr 2þ [8], and Ba 2þ [9], transition metals ions, such as Mn 2þ [10], Fe 2þ [11], Co 2þ [12], Ni 2þ [13], Zn 2þ [14], Nb 5þ [15], and W 6þ [16], also, rare earth cations, such as Ce 3þ [17,18], Gd 3þ [19], Nd 3þ [20], and Er 3þ [21] have been used to depress the formation of charge defects [16] or to modify dielectrics and thermophysical properties.…”