The effect of the medium on the kinetics of radiation polymerization of aminoalkyl monomers

Musayev, U.N.; Каримов, А.; Tillayev, R.S.; Usmanov, Kh.U.

doi:10.1016/0032-3950(74)90221-4

Cited by 2 publications

(2 citation statements)

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“…Fragments of IR spectra of the DMAPA-water systems recorded at 608C. Mole fraction of the amide: 0.012 (1), 0.028 (2), 0.047 (3), 0.103 (4), and 0.212 (5).…”

Section: Discussionmentioning

confidence: 99%

“…With the absence of hydrogen bond (H‐bond) donors in monomers with amide or amine functions the formation of H‐bonds between monomers and solvent molecules moves to the foreground. It was shown that the rate of homopolymerization of amine‐containing methacrylic esters and N,N‐dimethylacrylamide in water and various organic solvents increases with an increase in number of H‐bonds.…”

Section: Introductionmentioning

confidence: 99%

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Influences of monomer self‐association on the radical solution homopolymerization of N‐[3‐(dimethylamino)propyl](meth)acrylamide

Каморин

Rumyantsev

Казанцев

et al. 2016

J of Applied Polymer Sci

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The specific dependencies of the initial reduced polymerization rate on the initial monomer concentration were introduced for the radical homopolymerization of N‐[3‐(dimethylamino)propyl]acrylamide (DMAPA) and N‐[3‐(dimethylamino)propyl]methacrylamide (DMAPMA) in toluene, DMF, and water at 60 °С. The degree of the monomer self‐association and the ratio of the amides constituting various types of associates were evaluated using FT‐IR spectroscopy and computer simulation for the solutions of DMAPA and DMAPMA in toluene with different monomer concentrations. The hypothesis linking the type of predominant pre‐reaction monomer assemblies and the revealed concentration effects was proposed for the homopolymerization of aminoamide monomers and explaining unconventional experimental data. © 2016 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2017, 134, 44412.

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“…Fragments of IR spectra of the DMAPA-water systems recorded at 608C. Mole fraction of the amide: 0.012 (1), 0.028 (2), 0.047 (3), 0.103 (4), and 0.212 (5).…”

Section: Discussionmentioning

confidence: 99%

Section: Introductionmentioning

confidence: 99%