The equilibrium phase properties of the methanol-hydrogen sulfide binary system

Leu, Ah-Dong; Carroll, John J.; Robinson, Donald B.

doi:10.1016/0378-3812(92)85024-3

Cited by 28 publications

(15 citation statements)

References 8 publications

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“…The data agree very well with each other and with the predicted results of the PSRK model. Ž The results from the literature Leu et al, 1992;Laugier and . Richon, 1995 shown in Figures 1 and 3 were obtained with the direct static analytical method.…”

Section: Resultsmentioning

confidence: 98%

“…Gmehling 1994 . The modifications of the experimental setup as well as the raw data treatment, which is required for the indirect experimental method for determining the gas solubility in the liquid phase, are outlined by Fischer Leu et al 1992`and from this work ⅷ compared to predictions using the PSRK method.…”

Section: Apparatus and Proceduresmentioning

confidence: 99%

“…Shleinikov 1963, Vilcu et al 1991, Fischer 2002 , Zubchenko et al 1985, Schroedter 1991, Schlichting 1991 for the CO systems to other N-alkyl-2-pyrrolidone systems. drogen sulfide in methanol, and in benzene to validate the indirect static synthetic method and the data treatment pro-Ž cedure by comparing the results to the literature data Short et al, 1983;Schalk and Onken, private communication, 1973;Bezdel and Teodorovich, 1958;Yorizane et al, 1969;Leu et . al., 1992;Preuss and Moerke, 1990 for the H S q methanol 2 Ž .…”

Section: Introductionmentioning

confidence: 97%

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Solubility of H₂S and CO₂ in N‐octyl‐2‐pyrrolidone and of H₂S in methanol and benzene

et al. 2002

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Section: Resultsmentioning

confidence: 98%

Section: Apparatus and Proceduresmentioning

confidence: 99%

Section: Introductionmentioning

confidence: 97%

See 1 more Smart Citation

Solubility of H₂S and CO₂ in N‐octyl‐2‐pyrrolidone and of H₂S in methanol and benzene

et al. 2002

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“…Phase diagram calculations in the Gibbs ensemble are exemplified by the case of the H 2 S-methanol system at the temperature of 348 K, for which data are available [40]. As shown in Figure 9, the agreement of simulation results and experimental data is excellent.…”

Section: Gas Processingmentioning

confidence: 87%

“…a) Compressibility factor; b) Density. Phase diagram of the H 2 S-methanol mixture at the temperature of 348.15 K from Gibbs ensemble simulations (symbols) and experimental measurements (lines) [40]. Figure 10 Size distribution of methanol clusters in the liquid phase of a propane-methanol mixture at 2 MPa and 343 K. The straight line, which corresponds to the exponential formula shown, is a least squares fit of simulation results in this semilogarithmic plot.…”

Section: Gas Processingmentioning

confidence: 98%

Applications of Molecular Simulation in Oil and Gas Production and Processing

Ungerer¹,

Lachet²,

Tavitian³

2006

Oil & Gas Science and Technology - Rev. IFP

113

141

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Résumé -Applications de la simulation moléculaire à la production et au traitement du pétrole et du gaz -La simulation moléculaire est une technique émergente qui consiste à simuler un système de quelques centaines de molécules de façon très détaillée. Par des moyennes statistiques appropriées, on peut déterminer sur la base des résultats de cette simulation des propriétés d'équilibre et de transport qui peuvent être comparées à des résultats expérimentaux. Le but de l'article est de fournir au lecteur des notions de base sur les méthodes de simulation. Ensuite, des exemples d'application sont abordés qui couvrent divers domaines de l'industrie pétrolière. En ingénierie de réservoir, ces exemples ont trait aux propriétés d'équilibre des hydrocarbures lourds, aux propriétés thermiques des gaz naturels, ainsi qu'aux propriétés volumétriques et aux équilibres de phase des mélanges d'hydrocarbures et de gaz acides. Les applications du domaine de la production et du traitement sont illustrées par l'exemple des équilibres de phase impliquant le méthanol (couramment employé comme solvant ou comme inhibiteur d'hydrates) et celui de la solubilité des gaz dans les matériaux polymères à haute pression. En raffinage, c'est à la solubilité de l'hydrogène sulfuré dans les hydrocarbures à haute température que la simulation a été appliquée. Dans chacun de ces problèmes, la simulation a apporté des prédictions très utiles ainsi qu'une compréhension des causes profondes des relations entre la structure chimique et les propriétés des fluides. Elle fournit ainsi une voie intermédiaire à mi-chemin entre les mesures expérimentales et les modèles thermodynamiques classiques. Moins chère et plus rapide que de nouvelles mesures, elle peut améliorer la détermination des paramètres des modèles utilisés en routine. Abstract -Applications of Molecular Simulation in Oil and Gas Production and ProcessingMolecular simulation is an emerging technique which consists in performing a detailed simulation of microscopic systems involving typically a few hundreds of molecules. On the basis of these simulations

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Phase Equilibrium in the Systems Hydrogen Sulfide + Methanol and Carbon Dioxide + Methanol

Satyro

Carroll²

2014

Gas Injection for Disposal and Enhanced Recovery

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The equilibrium phase properties of the methanol-hydrogen sulfide binary system

Cited by 28 publications

References 8 publications

Solubility of H₂S and CO₂ in N‐octyl‐2‐pyrrolidone and of H₂S in methanol and benzene

Solubility of H₂S and CO₂ in N‐octyl‐2‐pyrrolidone and of H₂S in methanol and benzene

Applications of Molecular Simulation in Oil and Gas Production and Processing

Phase Equilibrium in the Systems Hydrogen Sulfide + Methanol and Carbon Dioxide + Methanol

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The equilibrium phase properties of the methanol-hydrogen sulfide binary system

Cited by 28 publications

References 8 publications

Solubility of H2S and CO2 in N‐octyl‐2‐pyrrolidone and of H2S in methanol and benzene

Solubility of H2S and CO2 in N‐octyl‐2‐pyrrolidone and of H2S in methanol and benzene

Applications of Molecular Simulation in Oil and Gas Production and Processing

Phase Equilibrium in the Systems Hydrogen Sulfide + Methanol and Carbon Dioxide + Methanol

Contact Info

Product

Resources

About

Solubility of H₂S and CO₂ in N‐octyl‐2‐pyrrolidone and of H₂S in methanol and benzene

Solubility of H₂S and CO₂ in N‐octyl‐2‐pyrrolidone and of H₂S in methanol and benzene