1977
DOI: 10.1002/pssb.2220830113
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The “extra” phase transition in TTF‐TCNQ

Abstract: High-resolution heat capacity data show an "extra" phase transition at 46 K in TTF-TCXQ powders in addition to the five phase transitions observed in bulk samples between 38 and 54 K.The "extra" phase transition in powders can be explained as a surface phase transition which corresponds to the bulk phase transition a t 48 K. I n powders the latter is shifted to 49 K by ferroelastic interactions between the "bulk" phase in grain interiors and the compressed surface phase.Hochauflosende Warmekapazitatsmessungen … Show more

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