The f → X transition in ICl

Stepp, Monica A.; Kremer, Martin; Tellinghuisen, Joel

doi:10.1016/0022-2852(91)90380-s

Cited by 9 publications

(2 citation statements)

References 19 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…Since then numerous experiments have been performed probing several valence, ion-pair, 11,17,[25][26][27][28][29][30][31][32][33][34][35] and Rydberg 31,36,37 states via numerous techniques such as visible absorption spectroscopy, emission spectroscopy, laser-induced fluorescence spectroscopy, vacuum ultraviolet spectroscopy, and micro-and millimeter-wave spectroscopy.…”

Section: Introductionmentioning

confidence: 99%

Ab initio potential energy curves of the valence, Rydberg, and ion-pair states of iodine monochloride, ICl

Καλέμος

Prosmiti

2014

The Journal of Chemical Physics

View full text Add to dashboard Cite

Extensive ab initio study of the valence and low-lying Rydberg states of BBr including spin-orbit coupling J. Chem. Phys. 124, 194307 (2006) We present for the first time a coherent ab initio study of 39 states of valence, Rydberg, and ionpair character of the diatomic interhalogen ICl species through large scale multireference variational methods including spin-orbit effects coupled with quantitative basis sets. Various avoided crossings are responsible for a non-adiabatic behaviour creating a wonderful vista for its theoretical description. Our molecular constants are compared with all available experimental data with the aim to assist experimentalists especially in the high energy regime of up to ∼95 000 cm −1 .

show abstract

Section: Introductionmentioning

confidence: 99%

Ab initio potential energy curves of the valence, Rydberg, and ion-pair states of iodine monochloride, ICl

Καλέμος

Prosmiti

2014

The Journal of Chemical Physics

View full text Add to dashboard Cite

show abstract

“…About 25 years ago two-step excitation began to be used to access several ion-pair states of ICl via the low-lying valence state A 1 3 [1][2][3]. Accurate spectroscopic constants and potential curves for some ion-pair and valence states are now available [4][5][6][7][8][9][10][11]. However, to our knowledge, the electric dipole moment function of only one ion-pair-valence transition in ICl, namely E 0 + ( 3 P 2 )-X 1 + , has been studied up to now [12,13].…”

Section: Introductionmentioning

confidence: 99%

Electric dipole moment function of the beta 1(³P₂)toA 1³Pi transition in ICl

Akopyan

Bibinov

Kokh

et al. 1999

J. Phys. B: At. Mol. Opt. Phys.

View full text Add to dashboard Cite

The optical-optical double-resonance technique has been used for measurements of emission spectra from separate vibrational levels of the 1(3P2) state of ICl (v´ = 12 and 14) populated via the A 1 3 state. The electric dipole moment function of the A transition has been determined over the range of the internuclear distance of 0.29-0.39 nm by means of simulation of the emission spectra from the state.

show abstract