2018
DOI: 10.1039/c7ra12700f
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The first colorimetric receptor for the B4O72− anion based on nitro substituted phenanthroimidazole ferrocene derivatives

Abstract: Four phenanthroimidazole ferrocene derivatives (2a–2d) were synthesized. Recognition of 12 anions by 2a–2d was investigated by UV-Vis absorption analysis, showing that 2b and 2d sensed B4O72− selectively with an obvious color change observed.

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Cited by 3 publications
(2 citation statements)
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“…Wu and co-workers designed four phenanthroimidazole derivatives with ferrocene scaffolds and examined their anion recognition properties towards twelve common anions such as F − , Cl − , Br − , SO 4 2− , OAc − , etc. [77]. Investigation of these common anions via spectroscope studies indicated that compounds 78b and 78d sensed B 4 O 7 −2 specifically and the sensing potential was realized through the naked eye, 1 H NMR, and various titration experiments, concluding that the binding force between B 4 O 7 −2 and 78b was hydrogen bonding (Figure 10).…”
Section: Chemosensing Applicationsmentioning
confidence: 98%
“…Wu and co-workers designed four phenanthroimidazole derivatives with ferrocene scaffolds and examined their anion recognition properties towards twelve common anions such as F − , Cl − , Br − , SO 4 2− , OAc − , etc. [77]. Investigation of these common anions via spectroscope studies indicated that compounds 78b and 78d sensed B 4 O 7 −2 specifically and the sensing potential was realized through the naked eye, 1 H NMR, and various titration experiments, concluding that the binding force between B 4 O 7 −2 and 78b was hydrogen bonding (Figure 10).…”
Section: Chemosensing Applicationsmentioning
confidence: 98%
“…Ferrocene‐based small molecules are the important class of materials due to their renowned redox behavior . Ferrocene‐based chalcones can undergo radical quenching and hydroxyl adduct formation .…”
Section: Ferrocene‐based Electro Responsive Materialsmentioning
confidence: 99%