The first specific probe for pyrrolidine with multifunction by the interaction mechanism of atomic economic reaction

Cao, Xi-Ying; Huang, Yan; Chen, Si-Hong; Yu, Shi-Wei; Chen, Zu-Jia; Li, Zhong-Hao; Zeng, Yu; Chen, Nan; Cao, Liang; Wang, Zhao-Yang

doi:10.1016/j.isci.2024.110024

iScience

2024

DOI: 10.1016/j.isci.2024.110024

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The first specific probe for pyrrolidine with multifunction by the interaction mechanism of atomic economic reaction

Xi-Ying Cao,

Yan Huang,

Si-Hong Chen

et al.

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2024

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Cited by 2 publications

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A Novel 2-Methylimidazole Promoted Oxyacyloxylation of α-Hydroxy Ketones and Anhydrides: An Easy Access to α-Acyloxy Ketones

Yu,

Li,

et al. 2024

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An efficient and operationally simple method for the synthesis of α-acyloxy ketones through the readily available 2-methylimidazole-promoted reaction of α-hydroxy ketones and anhydrides is developed. In the reaction, the anhydrides act as both a substrate and a solvent. The new method features good substrate tolerance, mild reaction conditions, readily accessible starting materials, and excellent yields, providing facile and green access to the targets. Importantly, the reaction also avoids the use of reagents with pungent odors, such as pyridine, in traditional esterification, which may promote the development of organocatalysis using nitrogen-containing heterocyclic compounds as catalysts.

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A Novel 2-Methylimidazole Promoted Oxyacyloxylation of α-Hydroxy Ketones and Anhydrides: An Easy Access to α-Acyloxy Ketones

Yu,

Li,

et al. 2024

Catalysts

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show abstract

Progresses in the Preparation of Chromone Compounds and Their Applications in Organic Synthesis

Li,

Zeng,

Zeng

et al. 2024

Chinese Journal of Organic Chemistry

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The first specific probe for pyrrolidine with multifunction by the interaction mechanism of atomic economic reaction

Cited by 2 publications

References 64 publications

A Novel 2-Methylimidazole Promoted Oxyacyloxylation of α-Hydroxy Ketones and Anhydrides: An Easy Access to α-Acyloxy Ketones

A Novel 2-Methylimidazole Promoted Oxyacyloxylation of α-Hydroxy Ketones and Anhydrides: An Easy Access to α-Acyloxy Ketones

Progresses in the Preparation of Chromone Compounds and Their Applications in Organic Synthesis

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