Transforming the energy sector to provide universal access to reliable and modern energy services is an essential task for Ukraine, one of the Eastern Partnership countries with heavy energy dependence. It will help accelerate the achievement of the Sustainable Development Goals. The paper is devoted to studying Ukraine’s readiness to generate sustainable energy compared to the EU and other Eastern Partnership countries and the development of an information base for monitoring the achievement of SDG7.The data from the World Energy Council (WEC), the International Energy Agency (IEA), and the State Statistics Service of Ukraine are analyzed. Thus, the study proposed to expand the list of national monitoring indicators that more fully reflect the social, economic, and environmental results of SDG7 “Affordable and clean energy” in Ukraine. The development of an information monitoring base expands the opportunities to assess the availability, sustainability, and balance of national energy policy in green economic transformation. Furthermore, the indicators of energy intensity, carbon intensity, as well as access to sustainable energy for the population and business are emphasized. The findings are aimed to raise the level of awareness of government agencies and make balanced decisions to accelerate the achievement of SDG7 in Ukraine.