In light of the increasing number of electric vehicles (EV), disorderly charging in mountainous cities has implications for the stability and efficient utilization of the power grid. It is a roadblock to lowering carbon emissions. EV aggregators are a bridge between EV users and the grid, a platform to achieve energy and information interoperability, and a study of the orderly charging of EVs to reach carbon emission targets. As for the objective function, the EV aggregator considers the probability of EV charging access in mountainous cities, the SOC expectation of EV users, the transformer capacity constraint, the charging start time, and other constraints to maximize revenue. Considering the access probability of charging for users in mountainous cities, the optimized Lagrange relaxation method is used to solve the objective function. The disorderly charging, centralized optimized charging, and decentralized optimized charging modes are investigated using simulation calculations. Their load profiles, economic benefits, and computational efficiency are compared in three ways. Decentralized optimal charging using the Lagrange relaxation method is shown to be 50% more effective and to converge 279% faster than centralized optimal charging.