Polynomial Decision Rules (DR) for the problems of discrete RZ (Return-to-Zero) signal distinction in asymmetric-excess non-Gaussian noise are proposed. A new approach is proposed, which is based on the use of a modified moment quality criterion of statistical hypothesis testing and the application of higher-order statistics to describe the characteristics of non-Gaussian noise. Simulation of the DR with different parameters of the signal and noise was carried out. It is shown that taking into account the coefficients of skewness and kurtosis of the non-Gaussian noise the efficiency of signal distinction increases with non-linear processing DR compared to known results, which are optimal for the Gaussian noise model. The conducted studies demonstrate a reduction in false decisions in the processing of RZ signals when considering the coefficients of skewness and kurtosis of non-Gaussian noise. Such an increase in efficiency can exceed twofold, depending on the noise parameters. It is shown that the efficiency of the proposed approach is much higher for small SNR (Signal-to-Noise Ratio) values, for example, less than 1.