2002
DOI: 10.1016/s0022-2860(01)00976-0
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The molecular structure and spectral studies of mercaptopyridyl-based ligands

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Cited by 23 publications
(20 citation statements)
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“…Access to tris(2-pyridylthio)methylcadmium compounds is provided by the reaction of tris(2-pyridylthio)methane ([Tptm]H) 7 with Cd[N(SiMe 3 ) 2 ] 2 to afford [Tptm]CdN(SiMe 3 ) 2 ( 1 ), as illustrated in Scheme 1. The molecular structure of [Tptm]CdN(SiMe 3 ) 2 has been determined by single-crystal X-ray diffraction (Figure 1), which clearly demonstrates that the [Tptm] ligand coordinates in a κ 4 manner, 8 thereby resulting in an atrane motif.…”
mentioning
confidence: 99%
“…Access to tris(2-pyridylthio)methylcadmium compounds is provided by the reaction of tris(2-pyridylthio)methane ([Tptm]H) 7 with Cd[N(SiMe 3 ) 2 ] 2 to afford [Tptm]CdN(SiMe 3 ) 2 ( 1 ), as illustrated in Scheme 1. The molecular structure of [Tptm]CdN(SiMe 3 ) 2 has been determined by single-crystal X-ray diffraction (Figure 1), which clearly demonstrates that the [Tptm] ligand coordinates in a κ 4 manner, 8 thereby resulting in an atrane motif.…”
mentioning
confidence: 99%
“…The bis(2-pyridylthio)methane, [(pyS) 2 CH 2 ] (1) and tris(2-pyridylthio)methane [(pyS) 3 CH] (2) ligands were prepared modifying the literature method [29]. Compounds 1 and 2 are air-and moisture-stable yellow microcrystalline solids; they are soluble in chlorinated solvents, diethyl ether, acetone and DMSO, but insoluble in acetonitrile, aromatic and aliphatic hydrocarbons and water.…”
Section: Resultsmentioning
confidence: 99%
“…The bis(2-pyridylthio)methane ligand was prepared by modification of the literature method [29]. The crude product was recrystallized in acetone/dichloromethane (1:1) yielding [(pyS) 2 …”
Section: Synthesis Of [(Pys) 2 Ch 2 ] (1)mentioning
confidence: 99%
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“…The bis(pyrimidin-2-ylthio)alkanes were synthesised following the experimental method outlined in the literature (de Castro et al , 2002 ). These ligands were purifi ed from a dichloromethane solution.…”
Section: Preparation Of Bis(pyrimidin-2-ylthio)alkanes and Organotin mentioning
confidence: 99%