The Next Generation: Synthesis, Characterization, and Structure of Metal Sulfide-Based Microporous Solids

Trimethylammonium Tin Sulfide

“…germanium sulfides (Bedard, Wilson, Vail, Bennett & Flanigen, 1989) have been reported. Recently, Parise, Ko, Rijssenbeek, Nellis, Tan & Koch (1994) solved the structure of tetramethylammonium tin sulfide (TMASnS-1) .…”

Two Supramolecular Architectures Containing Dinuclear Thiostannate [Sn2S6] Units

“…2a) [12]. The distortion of the octahedral environment of the [Co(dien) 2 ] 2+ ion in 1 can [Sn 2 S 6 ] 4− anion (Fig. 5) [6 -10], but the slightly elongated Sn1-S3 distance (2.349(2)Å) shows the influence of the coordination of the S3 atom to the Zn 2+ ion.…”

“…Following the demonstration by Bedard and coworkers in 1989 that template-directed synthesis can be applied to effect the crystallization of thio-and selenidometalates [2], a number of chalcogenidostannates have been synthesized by using organic amines as templates or structure-directing agents under hydro(solvo)thermal conditions [3]. Different organic amines can induce the same structure, but can also lead to different structures, which are related to the framework and the templating molecules.…”

“…The charge-balancing cations for SnS-1 are tetramethylammonium [4], tetraethylammonium [5], and protonated 1,8-diazabicyclooctane [5], while the cations for SnS-1 are tetrapropylammonium [5] and tetrabutylammonium [5]. When organic amines or transition metal complex cations were used instead of tetraalkyl-0932-0776 / 10 / 1000-1229 $ 06.00 c 2010 Verlag der Zeitschrift für Naturforschung, Tübingen · http://znaturforsch.com ammonium hydroxides, the dinuclear [Sn 2 S 6 ] 4− anion was obtained, as exemplified by (chaH) 4 Sn 2 S 6 (cha = cyclohexylamine) [6], (ddaH) 4 (2). Compound 1 is the only example of a thiostannate combined with two different cations.…”

Solvothermal Syntheses and Crystal Structures of New One-dimensional Selenogallates [bappH2][Ga2Se4] (bapp = 1,4-Bis-(3-aminopropyl)piperazine) and [Mn(en)3][Ga2Se5] (en = Ethylenediamine)

“…To develop traditional applications of microporous materials, great efforts have been employed to expand oxide open frameworks to their chalcogenide analogs. Since Bedard first reported microporous sulfido compounds by replacing O 2− by S 2− in an oxide framework in 1989 [2], a number of microporous chalcogenide open frameworks containing elements of Group 13 (e. g. gallium and indium) have been synthesized and characterized [3 -7]. These compounds have applications similar to zeolites because gallium and indium are in the same group as aluminum that is a key element in zeolite frameworks.…”