We have investigated the unique correlations between the excitonic characteristics and the interfacial charge distribution of InGaN/GaN multiple quantum well ͑MQW͒ light-emitting diodes ͑LEDs͒ over a broad range of temperatures. From the intensitycurrent-voltage characteristics of InGaN/GaN MQW LEDs, we observed a remarkable reduction and modulation in the distribution of the leakage charge over the light-emitting layer when adopting the multiquantum-barrier ͑MQB͒ structure. For nonunity ideality factors, which we extracted from current-voltage analyses, we found that it was the temperature that determined the carrier transport mechanism in the heterodevices. Furthermore, carrier tunneling processes, determined from the extent of charge accumulation, led to more-anomalous values of the pseudotemperature ͑T 0 ͒ and characteristic energy ͑E 0 ͒, which resulted from an abnormal deterioration of the luminescence intensities for a low effective density of states ͑DOS͒. We found that low-indiumcontent MQB devices exhibited inherently low values of T 0 over a broad range of temperatures. These values were associated with a low characteristic energy, a low charge population of the multilayer interface states, and a more-effective DOS. The signal intensity in the temperature-dependent electroluminescence spectrum deteriorated considerably at temperatures below 180 K, consistent with the presence of a greater number of charges at a higher value of E 0 . © 2010 The Electrochemical Society. ͓DOI: 10.1149/1.3494146͔ All rights reserved. Several recent attempts have been made to improve the structural and optoelectrical characteristics of nitride-based optoelectronic devices, which have many potential applications because of their thermal stability and high luminescence efficiency.1 Gallium nitridebased semiconductors are used in a variety of high-power and hightemperature devices because of their wide band gaps, high chemical stability, and relatively high saturation drift velocities.2,3 Highquality InGaN-based multiple quantum well ͑MQW͒ heterostructures are being investigated widely because of their potential applications in light-emitting diodes ͑LEDs͒ and laser diodes that can be operated at wavelengths from the visible to the ultraviolet. The presence of piezoelectric polarization, spontaneous polarization, and spinodal decomposition in wurtzite epitaxial heterolayers grown incoherently on ͑0001͒-oriented sapphire substrates leads to nitride materials and devices exhibiting inherently abnormal electronic and optical properties. [4][5][6][7][8] Nevertheless, in nanoscale crystalline structures, epitaxial heterosystems can feature misfit dislocations, which can lead to nonradiative recombination and decreased emission efficiency.Several technologies and applications have been developed to advance the performance and reliability of light-emitting devices. If we are to improve device performance even further, it will be essential that we understand the effects of these defects on the carrier injection mechanisms and exciton...