The phase split forced by salts or carbohydrates in nonaqueous systems

Sikorski, Patryk; Tomaszewski, Wojciech; Kosiek, Katarzyna; Hofman, Tadeusz

doi:10.1016/j.fluid.2023.113790

Fluid Phase Equilibria

2023

DOI: 10.1016/j.fluid.2023.113790

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The phase split forced by salts or carbohydrates in nonaqueous systems

Patryk Sikorski

Wojciech Tomaszewski

Katarzyna Kosiek

et al.

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2024

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Cited by 2 publications

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Ternary Liquid-Liquid Equilibria in a Few Nonaqueous Two-Phase Systems

Sikorski,

Kosiek,

Więckowski

et al. 2024

J Solution Chem

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The composition of coexisting phases for liquid-liquid and solid-liquid-liquid equilibria were measured at 298.2 and 313.2 K and under atmospheric pressure for the following systems: {sodium bromide + formamide + ethyl acetate}, {sodium thiocyanate + ethanol + (R)-limonene}, and {sodium thiocyanate + methanol + dibutyl ether}. These concentrations were determined mainly by chromatography and, for the first system, with the help of argentometric titration. The standard uncertainties in mole fractions varied between 0.001 and 0.008. The tie-line data were reproduced by the NRTL model with medium accuracy. Several empirical equations were used and tested to correlate binodal curves. The rational form of the equation, based on the liquid–liquid–solid tie-line, turned out to be the most adequate.

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Ternary Liquid-Liquid Equilibria in a Few Nonaqueous Two-Phase Systems

Sikorski,

Kosiek,

Więckowski

et al. 2024

J Solution Chem

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Temperature dependence of liquid–liquid equilibria in nonaqueous two–phase systems based on formamide

Sikorski,

Hofman

2024

The Journal of Chemical Thermodynamics

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The phase split forced by salts or carbohydrates in nonaqueous systems

Cited by 2 publications

References 99 publications

Ternary Liquid-Liquid Equilibria in a Few Nonaqueous Two-Phase Systems

Ternary Liquid-Liquid Equilibria in a Few Nonaqueous Two-Phase Systems

Temperature dependence of liquid–liquid equilibria in nonaqueous two–phase systems based on formamide

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