The photostability and degradation pathways of TKX-50 as a representative of nitrogen-rich energetic salts in aqueous solution

Chen, Jian‐Bo; Yan, Taishan; Wang, Chaofeng; Gao, Ruixia; Xu, Silong; Fan, Guijuan; Zhao, Xueyan; Liu, Yu

doi:10.1016/j.jphotochem.2021.113178

Cited by 5 publications

(2 citation statements)

References 33 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…It is universally acknowledged that the large-scale industrial production, storage, and transportation of EMs need a suitable temperature. Exceeding the temperature of decomposition of EMs will be prone to danger. ,, Therefore, analyzing the thermal stability of EMs is crucial to ensure their safe handling and usage. Another reason the TKX-50 is getting a lot of attention is that, as an EM, it has good thermal stability and high safety during storage and transportation.…”

Section: Explosive Safety and Thermal Decomposition Performance Of Tk...mentioning

confidence: 99%

An Overview on Synthesis, Explosion, Catalysis, Modification, and Application of Dihydroxylammonium 5,5′-Bistetrazole-1,1′-diolate (TKX-50)

Liu,

Chen,

Yang

et al. 2024

Chem. Mater.

View full text Add to dashboard Cite

Dihydroxylammonium 5,5′-bistetrazole-1,1′-diolate (TKX-50) is a new type of nitrogen-rich ionic salt in the field of energetic materials (EMs), which has beneficial application prospects in military, aerospace, and civilian blasting fields. TKX-50 has the characteristics of easy synthesis, high energy, low sensitivity and toxicity, and good comprehensive performance and is expected to replace the traditional EMs. However, in recent years, although the physicochemical properties and application of TKX-50 have been increasing, there are no relevant comprehensive in-depth reports to discuss the existing problems and countermeasures of TKX-50. Based on the current research progress of TKX-50, this review gives a detailed overview of the synthesis, chemical and physical properties, explosive performance, safety performance, thermal decomposition behavior, catalytic modification, composite modification, and applications of TKX-50. Moreover, we summarize the application advantages and existing problems of TKX-50 and provide a prospective on the development direction and research focus in the future.

show abstract

Section: Explosive Safety and Thermal Decomposition Performance Of Tk...mentioning

confidence: 99%

An Overview on Synthesis, Explosion, Catalysis, Modification, and Application of Dihydroxylammonium 5,5′-Bistetrazole-1,1′-diolate (TKX-50)

Liu,

Chen,

Yang

et al. 2024

Chem. Mater.

View full text Add to dashboard Cite

show abstract

“…Tetrazole hybrids' possible anticancer effect was discovered by a thorough analysis of their structure-activity relationship [20]. Furthermore, dihydroxylammonium 5,5 0bistetrazole-1,1 0 -diolate (TKX-50) has garnered a great deal of study interest because of its exceptional explosive performance [27].…”

Section: Introductionmentioning

confidence: 99%

Synthesis of a novel fused thieno‐pyrimidine with tetrazole analogs

Rajeswari,

Nagaraju,

Chunduri

et al. 2024

Journal of Heterocyclic Chem

View full text Add to dashboard Cite

This current investigation represents the new series of fused thieno‐pyrimidine with synthesized tetrazole analogs (6a–j). Intermediates thieno‐[2,3‐d]‐pyrimidine were prepared by utilizing the Gewald method, and tetrazole (5a–j) was synthesized by [3 + 2] cycloaddition of azide and appropriate nitrile. All the prepared novel molecules were characterized and confirmed by 1HNMR, 13CNMR, LC‐MS, and FT‐IR spectral analysis.

show abstract

Interpol review of the analysis and detection of explosives and explosives residues

Klapec

Czarnopys

Pannuto

2023

Forensic Science International: Synergy

View full text Add to dashboard Cite

The photostability and degradation pathways of TKX-50 as a representative of nitrogen-rich energetic salts in aqueous solution

Cited by 5 publications

References 33 publications

An Overview on Synthesis, Explosion, Catalysis, Modification, and Application of Dihydroxylammonium 5,5′-Bistetrazole-1,1′-diolate (TKX-50)

An Overview on Synthesis, Explosion, Catalysis, Modification, and Application of Dihydroxylammonium 5,5′-Bistetrazole-1,1′-diolate (TKX-50)

Synthesis of a novel fused thieno‐pyrimidine with tetrazole analogs

Interpol review of the analysis and detection of explosives and explosives residues

Contact Info

Product

Resources

About