The Reaction between Triethylsilane and Methyllithium

Gilman, Henry; Massie, Samuel P.

doi:10.1021/ja01210a501

Cited by 21 publications

(10 citation statements)

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“…Other work followed (24,25,26). The use of lithium metal in syntheses of silicon compounds of these types has also been investigated (6,9,27,28,29,30).…”

Section: Introductionmentioning

confidence: 99%

STUDIES IN SILICO-ORGANIC COMPOUNDS. VII. THE PREPARATION AND PROPERTIES OF CERTAIN SUBSTITUTED SILANES¹

Jenkins¹,

LAVERY²,

GUENTHER³

et al. 1948

J. Org. Chem.

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“…Other work followed (24,25,26). The use of lithium metal in syntheses of silicon compounds of these types has also been investigated (6,9,27,28,29,30).…”

Section: Introductionmentioning

confidence: 99%

STUDIES IN SILICO-ORGANIC COMPOUNDS. VII. THE PREPARATION AND PROPERTIES OF CERTAIN SUBSTITUTED SILANES¹

Jenkins¹,

LAVERY²,

GUENTHER³

et al. 1948

J. Org. Chem.

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“…No evidence for siliconcarbon cleavage was found in any of the hydrolyses. (3) The neutral equivalents were determined by electrometric titration and were based on the first hydrogen only. From the titration curves, the pKi and pK2 values were found, although the values must be considered only approximate.…”

Section: Discussionmentioning

confidence: 99%

Synthesis and Hydrolytic Stability of Some Organosilicon Phosphonate Esters

Barnes¹,

David²

1960

J. Org. Chem.

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“…With the smaller methyl or ethyl groups, all halogens are generally replaced. Even SiÀOR and SiÀH groups can react with organolithium compounds [54], [55].…”

Section: Syntheses With Alkali Metalsmentioning

confidence: 99%

Silicon Compounds, Organic

Rösch

John

Reitmeier

2000

Ullmann's Encyclopedia of Industrial Chemistry

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The article contains sections titled: 1. Introduction 2. Fundamental Synthetic Routes for Organosilicon Compounds 2.1. Direct Synthesis of Organohalosilanes 2.2. Grignard Synthesis 2.3. Syntheses with Alkali Metals 2.4. Addition Reactions (Hydrosilylation) 2.5. Substitution Reactions of Si−H Bonds 2.6. Coproportionation and Disproportionation 3. Silicon‐Functional Organosilicon Compounds 3.1. Halo‐ and Pseudohalosilanes 3.2. Alkoxy‐ and Aryloxysilanes 3.3. Acyloxysilanes 3.4. Oximino‐ and Aminoxysilanes 3.4.1. (Alkylamino)alkylsilanes 3.5. Organofunctional Organosilicon Compounds 4. Vinyl and Other Alkenyl Compounds 4.1. Organohalogenated Compounds 4.2. Nitrogen‐Containing Compounds 4.3. Cyanoalkyl Compounds 4.3.1. Organic Amino Compounds 4.3.2. Other Nitrogen Compounds 4.3.3. Organosulfur Compounds 4.4. Mercapto and Sulfidic Organofunctions 4.4.1. Compounds Containing Sulfur ‐ Oxygen Groups 4.4.2. Oxygen‐Containing Compounds 4.5. Epoxy and Other Oxy Compounds 4.5.1. Acrylates and Other Ester Functions 4.5.2. Acid Anhydrides and Other Carboxy Groups 4.5.3. Other Organofunctions 4.6. Other Organosilanes 5. Tetraorganosilanes 5.1. Production 5.1. Polysilanes 5.2. Uses 6. Silylating Agents 6.1. Silanes as Protecting Groups 6.1. Organosilicon Pharmaceuticals 6.1. Silanes for Modification of Organic Polymers 6.1.1. Cross‐Linking of Polyethylene 6.1.1. Donor Silanes 6.2. Silane Coupling Agents 6.2.1. Mode of Action 6.3. Analysis 6.4. Toxicology and Environmental Aspects 7. Economic Aspects 8. References

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The Reaction between Triethylsilane and Methyllithium

Cited by 21 publications

References 0 publications

STUDIES IN SILICO-ORGANIC COMPOUNDS. VII. THE PREPARATION AND PROPERTIES OF CERTAIN SUBSTITUTED SILANES¹

STUDIES IN SILICO-ORGANIC COMPOUNDS. VII. THE PREPARATION AND PROPERTIES OF CERTAIN SUBSTITUTED SILANES¹

Synthesis and Hydrolytic Stability of Some Organosilicon Phosphonate Esters

Silicon Compounds, Organic

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The Reaction between Triethylsilane and Methyllithium

Cited by 21 publications

References 0 publications

STUDIES IN SILICO-ORGANIC COMPOUNDS. VII. THE PREPARATION AND PROPERTIES OF CERTAIN SUBSTITUTED SILANES1

STUDIES IN SILICO-ORGANIC COMPOUNDS. VII. THE PREPARATION AND PROPERTIES OF CERTAIN SUBSTITUTED SILANES1

Synthesis and Hydrolytic Stability of Some Organosilicon Phosphonate Esters

Silicon Compounds, Organic

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STUDIES IN SILICO-ORGANIC COMPOUNDS. VII. THE PREPARATION AND PROPERTIES OF CERTAIN SUBSTITUTED SILANES¹

STUDIES IN SILICO-ORGANIC COMPOUNDS. VII. THE PREPARATION AND PROPERTIES OF CERTAIN SUBSTITUTED SILANES¹