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Jehle, Michael; Hoffmann, Anke; Kohlmann, Holger; Scherer, Harald; Röhr, Caroline

doi:10.1016/j.jallcom.2014.09.228

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Cited by 7 publications

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“…An oxyhydride series of Ba 21 M 2 O 5 H 12+ x (M = most of the p-block metals) contains a suboxide-like cluster [O 5 Ba 18 ] consisting of face-shared [OBa 6 ] octahedra. 25…”

Section: Introductionmentioning

confidence: 99%

A new family of anti-perovskite oxyhydrides with tetrahedral GaO₄ polyanions

et al. 2023

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“…An oxyhydride series of Ba 21 M 2 O 5 H 12+ x (M = most of the p-block metals) contains a suboxide-like cluster [O 5 Ba 18 ] consisting of face-shared [OBa 6 ] octahedra. 25…”

Section: Introductionmentioning

confidence: 99%

A new family of anti-perovskite oxyhydrides with tetrahedral GaO₄ polyanions

et al. 2023

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Metal Hydrides

Zhang

Verbraeken

Tassel

et al. 2017

Handbook of Solid State Chemistry

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This chapter discusses the various classes of hydride compounds, with a special focus on saline and metallic hydrides as well as oxyhydrides. It includes the following topics: thermodynamic stability, crystal chemistry, synthesis, and physical properties. The chapter also highlights recent progress in understanding hydride ion mobility in alkaline earth hydrides. It further deals with hydride compounds and in particular those containing alkali, alkaline earth, and transition and rare earth metals. The saline hydrides, that is, AH and AeH2(with ALi, Na, K, Rb, and Cs; AeMg, Ca, Sr, and Ba) are proper ionic materials, in which hydrogen is present as hydride anions, H−. Saline hydrides show many similarities with their halide analogues, especially concerning crystal and electronic structures and, perhaps to a lesser extent, physical attributes such as brittleness, hardness, and optical properties.

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