2024
DOI: 10.3390/cryst14070587
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The Synthesis and Crystallographic Characterization of Emissive Pt(II) and Au(I) Compounds Exploiting the 2-Ethynylpyrimidine Ligand

Sarah L. McDarmont,
Mary Jo McCormick,
Paul S. Wagenknecht
et al.

Abstract: The luminescent properties of Au(I) and Pt(II) compounds are commonly tuned by exploiting the alkynyl ligand with varying electron density. Herein, we describe the synthesis of three new emissive transition metal compounds, tbpyPt(C2pym)2, Ph3PAuC2pym, and Cy3PAuC2pym (where HC2pym = 2-ethynylpyrimidine), verified by 1H-NMR, EA, and a single-crystal X-ray diffraction analysis. The tbpyPt(C2pym)2 complex crystallized as an Et2O solvate in the orthorhombic space group Pbca with Z = 24 with three unique Pt(II) sp… Show more

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