The synthesis of iron and nickel carbonyl as calibration materials for spectroscopic systems

Tepe, Reha K.; Vassallo, D.; Jacksier, Tracey

doi:10.1016/s0584-8547(99)00174-3

Cited by 5 publications

(1 citation statement)

References 15 publications

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“…The approximate concentration of Ni(CO) 4 can be estimated using its gas-phase absorption coefficient of 4.1 × 10 4 atm -1 m -1 with the assumption that this value is approximately the same in aqueous solution. Curve resolution and integration of the area of the absorption in Figure produces a concentration estimate in the range of 0−3.5 × 10 -4 M or (0−39 ppm), as shown in Figure .…”

Section: Resultsmentioning

confidence: 99%

Spectroscopy of Hydrothermal Reactions 17. Kinetics of the Surface-Catalyzed Water−Gas Shift Reaction with Inadvertent Formation of Ni(CO)₄

Miksa

Brill

2001

Ind. Eng. Chem. Res.

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The rate constants and Arrhenius parameters for the reaction of CO in H 2 O were determined at 230-270 °C and 27.4 MPa by the use of a titanium flow reactor with real-time detection by infrared spectroscopy through sapphire windows. These rate measurements appear to be the first below the critical temperature of water. The zeroth-order kinetics model produced an Arrhenius activation energy of 32 ( 3 kcal/mol, which is in the range of previously reported values at higher temperatures, but the preexponential factor [ln(A, mol kg -1 s -1 )] of 20.5 is much larger. The higher overall reaction rate is consistent with heterogeneous catalysis by the reactor surfaces considering (1) the zeroth-order kinetics, (2) the high A factor, (3) the activation energy in the range for the water-catalyzed reactions, and (4) the previously determined dependence of the decomposition rate of the putative formic acid intermediate on the metal used to construct the cell. Extremely toxic Ni(CO) 4 was observed to form as a result of extraction of Ni from slightly corroded 316 stainless steel tubes that connected the cell/reactor to the flow control system. Ni(CO) 4 formed under somewhat limited conditions, but its occurrence forewarns of the potential hazard of hydrothermal processing when a high CO concentration might be present in a nickelcontaining reaction vessel.

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Section: Resultsmentioning

confidence: 99%

Spectroscopy of Hydrothermal Reactions 17. Kinetics of the Surface-Catalyzed Water−Gas Shift Reaction with Inadvertent Formation of Ni(CO)₄

Miksa

Brill

2001

Ind. Eng. Chem. Res.

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Sample Preparation and ICP‐MS Analysis of Gases for Metals

Jacksier

Tarutani²,

Carré

2013

Trace Analysis of Specialty and Electronic Gases

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Photochemical vapor generation of carbonyl for ultrasensitive atomic fluorescence spectrometric determination of cobalt

Deng

Zheng

Liu

et al. 2010

Microchemical Journal

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The synthesis of iron and nickel carbonyl as calibration materials for spectroscopic systems

Cited by 5 publications

References 15 publications

Spectroscopy of Hydrothermal Reactions 17. Kinetics of the Surface-Catalyzed Water−Gas Shift Reaction with Inadvertent Formation of Ni(CO)₄

Spectroscopy of Hydrothermal Reactions 17. Kinetics of the Surface-Catalyzed Water−Gas Shift Reaction with Inadvertent Formation of Ni(CO)₄

Sample Preparation and ICP‐MS Analysis of Gases for Metals

Photochemical vapor generation of carbonyl for ultrasensitive atomic fluorescence spectrometric determination of cobalt

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The synthesis of iron and nickel carbonyl as calibration materials for spectroscopic systems

Cited by 5 publications

References 15 publications

Spectroscopy of Hydrothermal Reactions 17. Kinetics of the Surface-Catalyzed Water−Gas Shift Reaction with Inadvertent Formation of Ni(CO)4

Spectroscopy of Hydrothermal Reactions 17. Kinetics of the Surface-Catalyzed Water−Gas Shift Reaction with Inadvertent Formation of Ni(CO)4

Sample Preparation and ICP‐MS Analysis of Gases for Metals

Photochemical vapor generation of carbonyl for ultrasensitive atomic fluorescence spectrometric determination of cobalt

Contact Info

Product

Resources

About

Spectroscopy of Hydrothermal Reactions 17. Kinetics of the Surface-Catalyzed Water−Gas Shift Reaction with Inadvertent Formation of Ni(CO)₄

Spectroscopy of Hydrothermal Reactions 17. Kinetics of the Surface-Catalyzed Water−Gas Shift Reaction with Inadvertent Formation of Ni(CO)₄