1981
DOI: 10.1021/ja00404a017
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The synthesis, redox properties, and ligand binding of heterobinuclear transition-metal macrocyclic ligand complexes. Measurement of an apparent delocalization energy in a mixed-valent copper(I)copper(II) complex

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Cited by 393 publications
(166 citation statements)
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“…Experimental Materials 2,6-Diformyl-4-methylphenol was synthesized according to the literature method [48]. 1,2-Diaminobenzene (SigmaAldrich) and zinc(II) nitrate hexahydrate (Merck, India) were purchased and used as such.…”
Section: Uv-visible Diffuse Reflectance Spectral Studymentioning
confidence: 99%
“…Experimental Materials 2,6-Diformyl-4-methylphenol was synthesized according to the literature method [48]. 1,2-Diaminobenzene (SigmaAldrich) and zinc(II) nitrate hexahydrate (Merck, India) were purchased and used as such.…”
Section: Uv-visible Diffuse Reflectance Spectral Studymentioning
confidence: 99%
“…Afterward, the hydroxymethyl reaction of some phenolic compounds with formaldehyde in basic conditions were further studied, however, there is lack of study about p-cresol, particularly no systematic study about the influences of sodium hydroxide amount, reaction temperature and time. Therefore, the method in previous reports for synthesis of 2,6-DHMMP using of p-cresol and formaldehyde is used nowadays [4][5][6][7][8] . Base on others and our previous work, DEPT135 was used in the present study to investigate the reaction process between p-cresol and formaldehyde in basic conditions.…”
Section: Introductionmentioning
confidence: 99%
“…Compared to the bulk of literature available o n dicopper(I1) complexes, very little has been reported o n heterodimetallic complexes of these ligands, 'Author to whom correspondence may be addressed. such coniplexes (21,72). T h e heterodimetallic complexes, having copper(I1) as one metal centre and the other metal centre varying among Mn(II), Fe(II), Co(II), and Ni(II), have been shown to exhibit considerable antife~roiiiagnetic coupling between the metal centres.…”
Section: Introductionmentioning
confidence: 99%
“…Dinuclear copper (11) complexes of these ligands show interesting magnetic and redox behaviour (10)(11)(12)(13)(14)(15)(16)(17)(18)(19). T h e dicopper cornplex of macrocyclic Schiff base ligand obtained tiom the condensation of 2-hydroxy-5-methylbenzene-1,3-dicarbaldehyde and 1,3-diamino-propane exhibits reversible oneelectron transfers at two different potentials, although both copper centres are identical with respect to ligand environment and geometry (20).…”
Section: Introductionmentioning
confidence: 99%