Theoretical Study on Electroreduction of CO2 to C3+ Catalyzed by Polymetallic Phthalocyanine Covalent Organic Frameworks (COFs) in Tandem

Du, Jinping; Guo, Ling

doi:10.1007/s10562-022-04229-3

Cited by 3 publications

(1 citation statement)

References 82 publications

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“…Du et al designed a catalyst with multiple active sites to reduce CO 2 to C 3 product. [185] They designed a FeCo─Pc─Ni─O─COF catalyst composed of a 2D COF constructed by a FeCo-Pc ligand and a square planar NiO 4 , which reduces CO 2 to n-propanol by a tandem reaction. The ∆G of CO* → CHO* and *CO + *CHO → *CO-CHO on Fe-Co-Pc are low, which means that C─C coupling is more likely to occur.…”

Section: Co 2 Reduction To C 3 /C 3+mentioning

confidence: 99%

Optimization Strategies of Covalent Organic Frameworks and Their Derivatives for Electrocatalytic Applications

Xiao,

Wang,

Guan

2023

Adv Funct Materials

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Covalent organic frameworks (COFs) are crystalline organic porous polymers that can be precisely integrated by building blocks to achieve pre‐designed composition, components, and functions, making them a powerful platform for the development of molecular devices in the field of electrocatalysis. The precise control of channel/dopant positions and highly ordered network structures of COFs provide an ideal material system for the applications of advanced electrocatalysis. In this paper, the topological structure design and synthesis methods of COFs are reviewed in detail, and their design principles are deeply analyzed. In addition, the applications of COFs and their derivatives in the field of electrocatalysis are systematically summarized and the optimization strategies are proposed. Finally, the application prospects of COFs and their derivatives in electrocatalysis and the challenges that may be encountered in the future are prospected, providing helpful guidance for future research.

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Section: Co 2 Reduction To C 3 /C 3+mentioning

confidence: 99%