Theoretical Study on the Pyrolysis of Sulphonyl Oximes in the Gas Phase

in Wiley Online Library (wileyonlinelibrary.com).Gas-phase pyrolysis of N-arylidine-N′-pyrimidin-2-yl-hydrazine derivatives 1a-e gave the corresponding arylnitriles 2a-e, 2-aminopyrimidine 3, 3-phenyl-1,2,4-triazolo[4,3-a]pyrimidines 4, 2-phenyl-1,2,4-triazolo [1,5-a]pyrimidines 5, 2,4,5-triphenyl-1H-imidazole 6, and 2,3-diphenylquinoline 7. The analyses of the reaction products are reported and used to elucidate the mechanism of the pyrolytic process.

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Product and Mechanism of Gas-phase Pyrolysis of 2-arylidinehydrazinopyrimidines: Interesting Route to Condensed Heterocycles[1]

Al-Awadi

Ibrahim

El‐Dusouqui

et al. 2014

J. Heterocyclic Chem.

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Gas-phase pyrolysis of benzimidazole derivatives: novel route to condensed heterocycles

et al. 2010

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An unexpected involvement of ethyl-2-cyano-2-(hydroxyimino) acetate cleaved product in the promotion of the synthesis of nitriles from aldoximes: a mechanistic perception

Dev

Palakurthy

Kumar

et al. 2013

Tetrahedron Letters

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Theoretical Study on the Pyrolysis of Sulphonyl Oximes in the Gas Phase

Cited by 4 publications

References 18 publications

Product and Mechanism of Gas-phase Pyrolysis of 2-arylidinehydrazinopyrimidines: Interesting Route to Condensed Heterocycles[1]

Product and Mechanism of Gas-phase Pyrolysis of 2-arylidinehydrazinopyrimidines: Interesting Route to Condensed Heterocycles[1]

Gas-phase pyrolysis of benzimidazole derivatives: novel route to condensed heterocycles

An unexpected involvement of ethyl-2-cyano-2-(hydroxyimino) acetate cleaved product in the promotion of the synthesis of nitriles from aldoximes: a mechanistic perception

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