Thermal decomposition of cyclobutanone. Comments

McGee, T. H.; Schleifer, A.

doi:10.1021/j100629a030

Cited by 6 publications

(1 citation statement)

References 2 publications

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“…A molecule that appears well suited to such a study is cyclobutanone. It is well established (7)(8)(9)(10) from conventional thermal decomposition studies that there are two clean, nonradical unimolecular modes of decomposition :…”

Section: Introductionmentioning

confidence: 99%

The decomposition of cyclobutanone vapor induced by infrared radiation from a pulsed CO₂ TEA laser

Back¹,

Back²

1979

Can. J. Chem.

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From the ratio of reaction [2] to reaction [I 1, information was obtained about the effective temperature of the decomposition and the energy of the decomposing molecules. With the laser beam unfocussed, the decomposition at pressures above about 3 Torr is adequately described as a thermal decomposition, controlled by the initial temperature attained and the rate of cooling of the irradiated gas. At lower pressures, and when the laser beam was focussed, direct excitation and decomposition of individual molecules by multiphoton absorption appears to be involved. . En se basant sur le rapport de la rkaction 2 ?I la rkaction 1, on a obtenu des informations concernant la tempkrature effective de la dkomposition et I'knergie des molkules qui se dkomposent. Lorsque le rayon laser n'est pas bien focalisk, on peut dkcrire adkquatement la dkomposition a des pressions supbieures a 3 Torr par une dkomposition thermique qui est contrBlQ par la tempkrature initiale obtenue et le taux de refroidissement des gaz irradiks. A des pressions infkrieures et lorsque le rayon laser est bien focalisk, il semble que I'excitation et la dkomposition directe de molkcules individuelles par une absorbtion multiphoton soient impliqukes. M. H. BACK[Traduit par le journal]

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Section: Introductionmentioning

confidence: 99%

The decomposition of cyclobutanone vapor induced by infrared radiation from a pulsed CO₂ TEA laser

Back¹,

Back²

1979

Can. J. Chem.

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Pulsed CO2 laser induced multiphoton decomposition of cyclobutanone: A comparison of predictions for three models of decomposition probability vs. fluence

1986

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The photochemistry of 1,2-cyclobutanedione in the gas phase

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Cao

1986

Journal of Photochemistry

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Thermal decomposition of cyclobutanone. Comments

Cited by 6 publications

References 2 publications

The decomposition of cyclobutanone vapor induced by infrared radiation from a pulsed CO₂ TEA laser

The decomposition of cyclobutanone vapor induced by infrared radiation from a pulsed CO₂ TEA laser

Pulsed CO2 laser induced multiphoton decomposition of cyclobutanone: A comparison of predictions for three models of decomposition probability vs. fluence

The photochemistry of 1,2-cyclobutanedione in the gas phase

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Thermal decomposition of cyclobutanone. Comments

Cited by 6 publications

References 2 publications

The decomposition of cyclobutanone vapor induced by infrared radiation from a pulsed CO2 TEA laser

The decomposition of cyclobutanone vapor induced by infrared radiation from a pulsed CO2 TEA laser

Pulsed CO2 laser induced multiphoton decomposition of cyclobutanone: A comparison of predictions for three models of decomposition probability vs. fluence

The photochemistry of 1,2-cyclobutanedione in the gas phase

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The decomposition of cyclobutanone vapor induced by infrared radiation from a pulsed CO₂ TEA laser

The decomposition of cyclobutanone vapor induced by infrared radiation from a pulsed CO₂ TEA laser