2023
DOI: 10.3390/inorganics11110434
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Thermochemistry, Structure, and Optical Properties of a New β-La2(SO4)3 Polymorphic Modification

Sofia A. Basova,
Maxim S. Molokeev,
Aleksandr S. Oreshonkov
et al.

Abstract: A new polymorphic modification of lanthanum sulfate was obtained by thermal dehydration of the respective nonahydrate. According to powder X-ray diffraction, it was established that β-La2(SO4)3 crystallized in the C2/c space group of the monoclinic system with the KTh2(PO4)3 structure type (a = 17.6923(9), b = 6.9102(4), c = 8.3990(5) Å, β = 100.321(3)°, and V = 1010.22(9) Å3). Temperature dependency studies of the unit cell parameters indicated almost zero expansion along the a direction in the temperature ra… Show more

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