Thermodynamics of complex formation of Ag(I). Part 9. Investigations on Ag(I)—thiourea—thioacetamide—halide systems in aqueous solution

Marco, Domenico De; Giannetto, Antonino; Donato, Giovanni

doi:10.1016/0040-6031(93)85095-q

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Triads Of Reactions Sub1

Chemical Reactions Involved For the Preparation Of Ag 2 S1

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1993

2014

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Cited by 4 publications

(2 citation statements)

References 7 publications

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“…The small differences do not allow to support the occurrence of two separated series but the phenomenon is worthy to be evidenced for it has been observed also in series of ligand coordination reactions to Ag(I) complex substrata (4,5) and because the behaviour is in contrast with the "rule" according to which the affinity of the entering ligand towards …”

Section: Triads Of Reactions Submentioning

confidence: 86%

Thermodynamic relationships in complex formation. IX. ΔH – ΔS and free energy relationships in mixed ligand complex formation reactions of Cd(II) in aqueous solution

Marco

Linert

2002

The Journal of Chemical Thermodynamics

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Section: Triads Of Reactions Submentioning

confidence: 86%

Thermodynamic relationships in complex formation. IX. ΔH – ΔS and free energy relationships in mixed ligand complex formation reactions of Cd(II) in aqueous solution

Marco

Linert

2002

The Journal of Chemical Thermodynamics

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“…Details of the above chemical processes have been well documented in the literature. 30,31 Here, only two typical reactions involved with a high R S/Ag value in our system were concerned:…”

Section: Chemical Reactions Involved For the Preparation Of Ag 2 Smentioning

confidence: 99%

Synthesis of normal and flattened rhombic dodecahedral Ag2S particles

Leng

Liu

et al. 2012

CrystEngComm

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Normal and flattened rhombic dodecahedral sub-micrometer Ag 2 S particles were synthesized by a facile hydrothermal method. The effects of molar ratio of thiourea (Tu) to AgNO 3 and volume of concentrated HCl aqueous solution on the morphologies of Ag 2 S particles have been systematically investigated. Experimental results indicated that the formation of soluble Ag-Tu complexes was a key issue to regulate the morphology of final products. The stability and decomposition of the soluble complexes were found to be dependent on the molar ratios of Tu to AgNO 3 and HCl. A body-centered cubic to monoclinic phase-transfer mechanism was proposed to explain the formation of regularly morphological Ag 2 S particles. Experiment section PreparationAll chemicals were of analytical grade and purchased from Chinese domestic suppliers. Ultra pure water with resistivity

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Thermodynamic relationships on complex formation

Marco

Giannetto

1993

Thermochimica Acta

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Thermodynamics of complex formation of Ag(I). Part 9. Investigations on Ag(I)—thiourea—thioacetamide—halide systems in aqueous solution

Cited by 4 publications

References 7 publications

Thermodynamic relationships in complex formation. IX. ΔH – ΔS and free energy relationships in mixed ligand complex formation reactions of Cd(II) in aqueous solution

Thermodynamic relationships in complex formation. IX. ΔH – ΔS and free energy relationships in mixed ligand complex formation reactions of Cd(II) in aqueous solution

Synthesis of normal and flattened rhombic dodecahedral Ag2S particles

Thermodynamic relationships on complex formation

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